The invention discloses an inorganic vitrification fiber modified nano base material and a preparing method thereof. The base material is prepared from organic silicon resin, organic solvent, vitrified beads, titanium dioxide, quartz sand, silicon carbide micro powder, nano cerium oxide, polyoxalate, light calcium carbonate, high-water-retention polyvinyl alcohol, dispersant, a thickening agent, a brightening agent, zinc sulfide, foamed aluminum, hydroxypropyl methyl cellulose, nanosilicon dioxide, a binding agent, cobalt naphthenate, molybdenum, nickel, propylene glycol and chromium. The nano base material is special for a building outer wall, performance in various aspects, such as high temperature resistance, fireproof performance, skid resistance, waterproof performance, moisture absorbing performance, abrasion resistance, oxidation resistance and corrosion resistance, of the building outer wall is effectively improved, and particularly thermal insulation performance is remarkably improved. The mechanical property of the material is enhanced by adopting pitch-based carbon fiber, and harmful gas and dust substances in tail gas can be adsorbed and removed greatly.