The application provides a method for co-production of battery-grade
nickel sulfate and battery-grade
iron phosphate, comprising the following steps: 1) performing first acid leaching treatment on a
nickel-iron
alloy pair by using an acid liquor to obtain a first acid leaching liquor and a first acid leaching residue; 2) performing second acid leaching treatment on the first acid leaching residue by using an
oxidizing agent and an acid liquor to obtain a second acid leaching liquor and a second acid leaching residue; 3) performing extraction treatment on a mixed liquor comprising the first acid leaching liquor and the second acid leaching liquor by using an
ion exchange resin to obtain a
raffinate comprising
ferrous ions; performing oxidation treatment on a
system comprising the
raffinate and a
phosphorus source to obtain
iron phosphate; 4) performing cleaning treatment on the
ion exchange resin after the extraction treatment by using an acid liquor, then performing stripping treatment on the
ion exchange resin by using an acid liquor and performing cooling
crystallization treatment on a stripping liquor comprising
nickel ions to obtain nickel
sulfate. The method provided by the application has high nickel
leaching rate and iron
leaching rate, the prepared nickel
sulfate and
iron phosphate have high purity, and the process flow is simple.