The invention discloses a synthetic method of
pollution-resistant deeply-softened
chelating resin. The synthetic method comprises the following steps: preparing an
oil phase by adopting a
styrene monomer, a
divinyl benzene crosslinking agent, a pore-
foaming agent and an initiating agent; preparing a water phase by adopting water, a dispersant and NaCl; adding the
oil phase into the water phase, lowering the temperature after a temperature rising process, discharging, washing, extracting,
drying and screening to obtain
polystyrene series
styrene-
divinylbenzene copolymers of the
pollution-resistant deeply-softened
chelating resin; then performing chloromethylation reaction, and transforming to obtain
polystyrene series chloromethylated beads; performing stirring expansion on the
polystyrene series chloromethylated beads by using dichlorethane, adding N-
hydroxymethyl phthalimide, dropwise adding a catalyst, heating, preserving the temperature, cooling, pumping out
mother liquor, adding water, performing reduced pressure
distillation, and cleaning; and adding 25% caustic soda liquid, heating, stabilizing, washing with water, adding a
chloroacetic acid solution to perform
chelation reaction, heating, preserving the temperature, washing with water, performing acid regulation, washing with water, performing alkali regulation, washing with water until the mixture is neutral, and discharging for
package to obtain the
pollution-resistant deeply-softened
chelating resin.