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63results about How to "High interfacial tension" patented technology

A preparation method of a ceramic coated separator for lithium ion batteries

The invention discloses a preparation method of a ceramic coating separator for lithium ion batteries and belongs to the technical field of lithium ion battery separator production. The method involves a polymer porous base film, a polymer glue applied on one or both sides of the base film surface, a ceramic coating applied on the surface of the polymer glue, and a PVDF and its copolymer glue applied on the other side of the ceramic coating surface and the base film surface, wherein the PVDF and its copolymer glue are coated on the other side of the ceramic coating surface and the base film surface. The inorganic ceramic particles adopted by the invention are non-spherical and multi-particle, which can greatly improve the porosity of the ceramic coating, increase the lithium ion transit property, improve the liquid absorption rate of the diaphragm, and improve the rate performance and cycle life of the lithium ion battery. As the structure design of the ceramic coat diaphragm of the invention can increase the adhesive force of the ceramic coating and the polymer porous base membrane, the adhesive strength of the diaphragm and the positive and negative electrode sheets is improved,the problems of powder dropping and coating peeling off are effectively improved, the high-efficient automatic assembly of the lithium battery is realized, and the heat resistance and electrochemicalstability of the diaphragm are greatly improved.
Owner:HENAN FUSEN NEW ENERGY TECH

High-intensity urea-formaldehyde resin microcapsule and preparation method thereof

The invention relates to a high-intensity urea-formaldehyde resin microcapsule. Titanium dioxide or silicon dioxide inorganic nanoparticles with particle diameter of 10 to 50 nm are doped in the wall material of the microcapsule. A preparation method of the high-intensity urea-formaldehyde resin microcapsule comprises the following steps of: mixing urea and formaldehyde according to a molar ratio of the urea to the formaldehyde of 1:1.75; adjusting the pH value to 8.5 to 9.0; stirring at the constant temperature of between 70 and 75 DEG C for 1 hour; diluting by adding distilled water to obtain urea-formaldehyde prepolymer solution with mass concentration of 35 to 60 percent; taking 10 to 20 milliliters of the urea-formaldehyde prepolymer solution and adjusting the pH value to 4.0 to 4.2; reacting at the temperature of between 23 and 26 DEG C for 1 hour to obtain water-soluble urea-formaldehyde resin; dispersing the inorganic nanoparticles into an oil phase to prepare 0.04 to 0.2 mass percent of inorganic particle dispersion liquid; adding 40 milliliters of 7.3 mass percent of deionized water solution of a system modifier into the water-soluble urea-formaldehyde resin; adding 4.5 milliliters of inorganic particle dispersion liquid dropwise under stirring to form emulsion and then adjusting the pH value to 3.0 to 3.5; reacting at the temperature of between 23 and 26 DEG C for 1 hour; adding 0.3 to 3 grams of curing agent; heating the product to 45 to 50 DEG C; performing heat-preserving reaction for 2 hours; and performing suction-filtration and drying to obtain the urea-formaldehyde resin microcapsule, of which the wall material is doped with the inorganic nanoparticles.
Owner:SOUTHEAST UNIV

Method for preparing high-crystallinity covalent organic framework film by using ionic liquid-water interface

The invention discloses a method for preparing a high-crystallinity covalent organic framework membrane by using an ionic liquid-water interface. The method comprises the following steps of: dissolving an aldehyde monomer in a hydrophobic ionic liquid to obtain a solution A; dissolving an amine monomer and an acid catalyst p-toluenesulfonic acid in deionized water to obtain a solution B; transferring the solution A into a reactor, adding deionized water to the surface of the solution A, layering, adding the solution B to the upper part of the deionized water layer, and performing a reaction for more than 3 days in the reactor under the condition of still standing at room temperature, so as tosynthesize the covalent organic framework membrane by using a double-diffusion control mechanism that the hydrogen-bond interaction of the acid catalyst and the amine monomer and the high viscosity of hydrophobic ionic liquid are utilized and the diffusion rates of the two monomers are limited at the same time. The covalent organic framework membrane prepared by the method has very high crystallinity, the specific surface area of themembrane is increased by 4 times compared with that of a covalent organic framework membrane synthesized on a traditional dichloromethane-water interface, and the solvent flux is also increased by 2 times under the condition that dye interception is not influenced.
Owner:HENAN NORMAL UNIV

Environment-friendly water-based fire extinguishing agent for fire protection

The invention belongs to the technical field of fire-fighting foam, and discloses a fire-fighting environment-friendly water-based fire extinguishing agent. The fire extinguishing agent is prepared from the following raw materials in percentage by weight: 15 to 40 percent of fatty acid amide, 5 to 10 percent of phosphate, 5 to 10 percent of foaming agent, 3 to 5 percent of fatty alcohol, 1 to 3 percent of pH regulator, 0.5 to 0.8 percent of preservative, 0.2 to 0.5 percent of stabilizer, 10 to 15 percent of organic solvent and the balance of water. According to the invention, fatty acid amide is used as a main surfactant and cooperates with other assistants, so the prepared fire extinguishing agent has the advantages of low interfacial tension, high wettability and high foaming and fire extinguishing speed; phosphate is added into the fire extinguishing agent, so that the flame retardance can be improved, the wettability of the system is improved, and the foaming property and the fire extinguishing property of the system are promoted to a certain extent; the addition of the fatty alcohol can increase the emulsifying property of the system, reduce the interfacial tension of oil and water and reduce the height of an emulsifying layer of mixed oil and water; the emulsifying effect is promoted by controlling the addition amount of the fatty alcohol, but the height of an oil-water mixing layer is not increased, and fire extinguishment and field treatment after fire extinguishment are facilitated.
Owner:四川科宏达集团有限责任公司

Preparation method of flat acrylic fiber

The invention relates to a preparation method of flat acrylic fiber. The preparation method is characterized by sequentially including following steps: spinning, coagulating, and forming: extruding polymer dope of 10-13.5wt% in polyacrylonitrile copolymer content into coagulating bath by a rectangular-hole spinneret plate after being treated specially, and forming primary fiber through double diffusion coagulating; drying for densification after water washing and drafting, and performing heat setting; oiling, winding, and drying: subjecting fiber after being treated thermally to soak-oiling and winding sequentially to endow with processability after spinning to obtain the flat acrylic fiber. Compared with existing rectangular-hole spinneret plates, the preparation method has the advantagesthat the surface of a tantalum metal spinneret plate is improved through nitriding and siliconing, in this way, temperature difference of the polymer dope in the spinneret plate and the coagulating bath is increased from delta 45-50 DEG C before treatment to delta 55-60 DEG C, contact angle of the dope at an orifice outlet is increased by 30 degrees, rheological performance of the dope is improved, and production stability and quality improvement of the flat fiber are ensured.
Owner:CHINA PETROLEUM & CHEM CORP

Radial electrospinning nozzle based on differential polygonal blades

The invention relates to a radial electrospinning nozzle based on a differential polygonal blade, belonging to the technical field of nanofiber preparation, which is composed of a cylindrical tube anda radial spinneret with a differential polygonal blade at the top. The radial spinneret is composed of a plurality of radial blades with the same structure evenly distributed along the circumference,a plurality of differential polygonal blades are equally spaced at the top of each radial blade, the radial spinneret is located at the upper or lower part of the cylindrical tube, and the inner diameter of the joint is equal, and the connection is tight and smooth, so that the barrier-free transport of the electrospinning fluid can be realized. The radial spinneret is composed of a plurality ofradial blades with the same structure uniformly distributed along the circumference. The radial electrospinning nozzle based on the differential polygon blade has a large inner diameter, is favorablefor avoiding the clogging problem, and can electrospin the high-concentration spinning solution; The radial spinneret can stabilize the droplets and produce multiple spinning jets, resulting in high spinning yield. The tubular structure can realize sealed and controllable liquid supply, and the solvent is not easy to volatilize. Differential polygon blades with tips can generate higher field strength and reduce energy consumption.
Owner:WUHAN TEXTILE UNIV

Method for preparing colloidal crystal by emulsion suspension

The invention discloses a method for preparing a colloidal crystal by emulsion suspension. The method comprises the following steps: step 1, preparing a colloidal particle suspension emulsion; step 2,injecting the colloidal particle suspension emulsion into the lower surface of a membrane substrate to be coated, and enabling the suspension emulsion to be suspended at the lower surface of the membrane substrate to be coated under attractive force of the membrane substrate to be coated to the suspension emulsion; and step 3, transferring the to-be-coated membrane substrate suspending the suspension emulsion into an atmosphere with a temperature of 40-150 DEG C, and making the dispersion liquid in the suspension emulsion evaporated to obtain the colloidal crystal. According to the invention,colloidal particles are regularly arranged under actions of force such as capillary force and self gravity generated by evaporation of the dispersion liquid, so that the colloidal crystal is prepared, when the suspension emulsion is suspended downwards, the interfacial tension formed between the liquid surface and the substrate, namely, the capillary force which drives small spheres arranged, canbe increased under actions of the gravity of the dispersion liquid, so that the surface uniformity of the film-forming colloid crystal is improved; and the method has the advantages that the preparation process is simple, the efficiency is high, and complex equipment is not needed.
Owner:(CNBM) BENGBU DESIGN & RES INST FOR GLASS IND CO LTD

Radial electrospinning nozzle based on rectangular blades

The invention relates to a radial electrospinning nozzle based on rectangular blades, and belongs to the field of nanofiber preparation. The nozzle comprises a radial spinneret and a cylindrical tube.The radial spinneret is composed of a plurality of uniformly distributed rectangular blades of the same structure, each rectangular blade opens to the outer side to be radial at a certain angle, theradial spinneret is closely and smoothly connected with the cylindrical tube, and barrier-free transport of a spinning fluid can be achieved. The radial electrospinning nozzle based on rectangular blades has the large inner diameter, the needle blocking problem is avoided conveniently, and electrostatic spinning can be conducted on a high-concentration spinning solution system; the radial spinneret with the rectangular blades has the function of stabilizing liquid droplets; meanwhile, the area of the spinning liquid surface is increased, multiple spinning jets can be generated, and the spinning output can be increased conveniently; closed and controllable liquid supply can be achieved by means of an injection pump, and a solvent is not likely to be volatilized; the rectangular blades havethe point effect, and the energy consumption can be lowered; in addition, the radial electrospinning nozzle based on the rectangular blades can be used for alternating current spinning.
Owner:WUHAN TEXTILE UNIV

Sulfuric acid etching process method

The invention discloses a sulfuric acid etching process method, which comprises the following steps of: in an etching process of a silicon wafer, setting the initial proportioning amount of pure waterin an etching tank to be 220+ / -50g / L, the initial proportioning amount of hydrofluoric acid to be 100+ / -50g / L, the initial proportioning amount of nitric acid to be 510+ / -50g / L and the initial proportioning amount of sulfuric acid to be 220+ / -50g / L; the pure water supplementing amount of the etching tank is set to be 0 mL / piece, the hydrofluoric acid supplementing amount is set to be 4.0+ / -2.0 mL / piece, the nitric acid supplementing amount is set to be 5.0+ / -2.0 mL / piece, and the sulfuric acid supplementing amount is set to be 1.5+ / -1.0 mL / piece; and according to the method, equipment (suitable for rollers of different types or tooth depths) does not need to be improved, sulfuric acid only needs to be supplemented in the primary preparation and production process of the etching groove, polishing of the back face of the silicon wafer and improvement of the reflectivity can be achieved through comprehensive optimization and adjustment of the process temperature, the circulating flow andthe water film amount, then the purpose of improving the conversion efficiency of the single crystal cell is achieved, and various electrical parameters of the prepared silicon wafer completely meetthe original requirements, and the process is simple and easy to implement.
Owner:平煤隆基新能源科技有限公司

Radial electrospinning nozzle based on differential rhombus blades

The invention relates to a radial electrospinning nozzle based on differential rhombus blades, and belongs to the technical field of nanofiber preparation. The radial electrospinning nozzle based on differential rhombus blades is composed of a cylinder tube and a radial spinneret with differential rhombus blades, wherein the radial spinneret is composed of a plurality of radial blades which have the same structure and are uniformly distributed along the circumference; a plurality of differential rhombus blades are arranged at the top of each radial blade at equal interval; the radial spinneretis arranged at the upper part or the lower part of the cylinder tube; and the radial spinneret and the cylinder tube have the same inner diameter at a joint and are closely and smoothly connected, thus being able to realize unobstructed transport of spinning fluids. The radial electrospinning nozzle based on differential rhombus blades has a large inner diameter, thus being beneficial to avoidance of the clogging problem, and can electrospin high concentration spinning solution. Besides, the radial spinneret has the function of stabilizing droplets, and can produce multiple spinning jets, thus being large in the spinning yield. Moreover, the tubular structure of the radial electrospinning nozzle based on differential rhombus blades can achieve closed and controllable liquid supply, and the solvent is not volatile, and the differential rhombus blades have tips to produce higher field strength, thus being able to reduce energy consumption.
Owner:WUHAN TEXTILE UNIV

Horn-shaped electrospinning nozzle with differential polygon blades at top

The invention relates to a horn-shaped electrospinning nozzle with differential polygon blades on the top and belongs to the technical field of nanofiber preparation. The horn-shaped electrospinning nozzle is formed by a cylinder tube, a horn mouth and the differential polygon blades; the differential polygon blades are evenly distributed at the top of the big opening of the horn mouth circumferentially, the horn mouth is located on the upper portion or the lower portion of the cylinder tube, the small opening of the horn mouth is equal to the joint of the cylinder tube in inner diameter withcontact and smooth connection, and barrier-free transportation of spinning fluid can be realized. The horn-shaped electrospinning nozzle with the differential polygon blades at the top is large in theinner diameter, so that plugging of needles can be favorably avoided, and electrospinning can be performed on high-concentration spinning solutions; the differential polygon blades at the top of thespinning nozzle has the function of stabilizing droplets, the area of spinning fluid level is enlarged, multiple spinning jets can be generated, and spinning production is increased; closed and controllable fluid supply can be realized through the tubular structure, and solvents are less prone to volatilization; the differential polygon blades at the top of the horn mouth are provided with tips, so that higher field intensity can be produced, and energy consumption can be reduced.
Owner:WUHAN TEXTILE UNIV

Covering comprehensive material as well as preparation method and application thereof

InactiveCN109988930AImprove refinement metamorphic effectImprove the efficiency of spoilage treatmentMANGANESE ACETATESlag
The invention discloses a covering comprehensive material as well as a preparation method and application thereof, and relates to the field of aluminum alloy modifiers. The covering comprehensive material is prepared from the following raw materials of, in percentage by weight, 3%-9% of aluminum chloride, 0.5%-0.8% of manganese acetate, 2%-9% of sodium nitrate, 0.11%-0.18% of zinc fluoride, 8%-12%of potassium chloride, 12%-16% of sodium chloride, 6%-10% of sodium fluoride, 9%-18% of composite powder and the balance sodium fluoroaluminate; when the covering comprehensive material is used as the modifier, the modification refinement elements are matched with each other, so that the modification effect is excellent; when the modifier is used as a covering agent, so that the melt can be prevented from being absorbed and oxidized, the heat preservation effect is good, the exhaust emission is promoted, the potash feldspar clay powder in the raw materials can be used as a modifier carrier toremove gas and remove slag, the smelting step is simplified, the smelting efficiency is improved, and the alloy hardness can be remarkably improved by the rich aluminum oxide and silicon oxide. Whenthe aluminum alloy is smelted, the strength, the plasticity and the hardness of an aluminum alloy casting can be remarkably improved by using the covering comprehensive material.
Owner:ANHUI POLYTECHNIC UNIV MECHANICAL & ELECTRICAL COLLEGE
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