The application provides a preparation and application of an anti-aging starch-based emulsifier, wherein the preparation method comprises five steps of amorphization, oxygen-free pyrolysis, low-temperature gelatinization, centrifugal separation and spray drying; the amorphization and overheated steam treatment are combined, the pyrolysis efficiency and solubility of starch are improved, and browning and peculiar smell are prevented; the starch granules after pyrolysis are subjected to low-temperature gelatinization and centrifugal separation to obtain a soluble starch solution with suitable molecular weight and chain length distribution, and the starch granules form granular molecular clusters in water, adsorb and stabilize the oil-water interface; due to strong adsorption force, the starch molecular clusters are difficult to be widely crosslinked, and the aging of the starch emulsifier is effectively inhibited; the starch-based emulsifier provided by the application has the characteristics of anti-aging and pure naturalness, and is suitable for food, pharmaceutical and other industries.