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543 results about "Hydroxyl-terminated polybutadiene" patented technology

Hydroxyl-terminated polybutadiene (HTPB) is an oligomer of butadiene terminated at each end with a hydroxyl functional group. It reacts with isocyanates to form polyurethane polymers. HTPB is a translucent liquid with a color similar to wax paper and a viscosity similar to corn syrup. The properties vary because HTPB is a mixture rather than a pure compound, and it is manufactured to meet customers' specific requirements. A typical HTPB is R-45HTLO. This product consists of oligomeric units typically containing 40–50 butadiene molecules bonded together, with each end of the chain terminated with a hydroxyl [OH] group...

High-cis-1,4-content hydroxyl-terminated polybutadiene liquid rubber and preparation method thereof

The invention discloses a high-cis-1,4-content hydroxyl-terminated polybutadiene liquid rubber and a preparation method thereof. The method includes following steps: (1) preparing epoxidized butadiene rubber from butadiene rubber; (2) preparing high-cis-1,4-content aldehyde group-terminated polybutadiene liquid rubber from the epoxidized butadiene rubber; (3) preparing high-cis-1,4-content aldehyde group-terminated polybutadiene liquid rubber from the butadiene rubber in a one-pot manner; (4) reducing the high-cis-1,4-content aldehyde group-terminated polybutadiene liquid rubber to prepare the high-cis-1,4-content hydroxyl-terminated polybutadiene liquid rubber. In the method, the high-cis-1,4-content hydroxyl-terminated polybutadiene liquid rubber is prepared from the butadiene rubber and the content of cis-1,4 can reach 95.0-99.0%. A number-average molecular weight of the high-cis-1,4-content hydroxyl-terminated polybutadiene liquid rubber can be regulated between 2000 g/mol and 10000 g/mol. A molecular weight distribution is 1.2-3.0 and a degree of functionality is 1.9-2.2. On the basis of excessive supply in raw rubber of butadiene rubber and increased tensing situation of petroleum sources, by means of the method, the high-cis-1,4-content hydroxyl-terminated polybutadiene liquid rubber can be prepared through oxidative pyrolysis of the butadiene rubber, so that the method has a quite important practical significance.
Owner:ZHEJIANG UNIV

Preparation for low molecular weight hydroxy-terminated polybutadiene

The invention provides a method for preparing hydroxyl-terminated polybutadiene of low molecular weight. The method adopts butadiene as a monomer, lithium alkylide of aliphatic series which contains silane protecting hydroxyl as an evocating agent, an organic non-polar compound as a solvent, an epoxy compound as an end capping reagent and fluoride as a detaching reagent for protecting groups. Anion polymer technology is adopted and polymerization is carried out at a temperature of 20 to 80 DEG C in the environment of inert gases; a prepolymer obtained goes through acid hydrolysis and a series of hydroxyl-terminated polybutadiene fluid rubber with narrow molecular distribution and controllable molecular weight is obtained. In the process of preparing hydroxyl-terminated polybutadiene polymer of the invention, the polymer does not encounter with a fake gel phenomenon during the process of end capping and detaching protecting group and the polymerization process is easy for control; the micro-structure of molecular chains is adjustable and controllable. The obtained hydroxyl-terminated polybutadiene has a molecular weight distributing index less than or equal to 1.2; the average functionality is close to 2; the cured products of hydroxyl-terminated polybutadiene have extremely good mechanical property and can be applied to the fields of rocket technology, optical fiber communication technology, etc.
Owner:SINOPEC LANZHOU GASOLINEEUM CHEM IND CORP

Ultra-flexible polyurethane acrylate resin and liquid-state optical adhesive composition thereof

The invention discloses ultra-flexible polyurethane acrylate resin and a liquid-state optical adhesive composition thereof, and belongs to the technical field of polymer synthesis. The ultra-flexible polyurethane acrylate resin has a refractive index of 1.51, resin chromaticity APHA of 30, viscosity of 0.25 million of mPa.s, Tg lower than minus 40 DEG C and molecular weight of 10000-100000. The ultra-flexible polyurethane acrylate resin is prepared from the raw materials comprising liquid-state hydroxyl-terminated polybutadiene, aliphatic and/or alicyclic diisocyanate, a polymerization inhibitor, a catalyst, a solvent and hydroxyalkyl acrylate. A preparation method for the ultra-flexible polyurethane acrylate resin comprises the following steps: uniformly mixing the liquid-state hydroxyl-terminated polybutadiene, the aliphatic and/or alicyclic diisocyanate, the polymerization inhibitor, the catalyst and the solvent to obtain a mixture; then, adding the hydroxyalkyl acrylate into the mixture to react, thereby obtaining the ultra-flexible polyurethane acrylate resin. The ultra-flexible polyurethane acrylate resin has Tg lower than minus 40 DEG C, good flexibility and resin chromaticity APHA of 30. The liquid-state optical adhesive prepared by taking the resin disclosed by the invention as a main component has the advantages of high bonding strength and low shrinkage ratio.
Owner:深圳市浩力新材料技术有限公司

Method for preparing high performance urethane elastomer for thermal barrier coating

The invention provides a preparation method of a thermal insulation coating high-performance polyurethane elastomer. After the reaction of terminal hydroxyl polybutadiene liquid rubber and polyisocyanate, polyurethane is added for reaction for 3 to 4.5 hours at 85 to 90 DEG C to produce isocyanate-terminated prepolymer; a certain amount of heat insulating filler is added in the prepolymer and is mixed evenly to produce component A; chain extender, antioxidant, curing agent and solvent are mixed evenly according to a certain portion to produce component B; the component A and the component B with the weight portion of 3: 1 to 6: 1 are mixed, stirred evenly, cured at room temperature to produce the thermal insulation coating high-performance polyurethane elastomer. The process of the invention used to synthesize the thermal insulation coating high-performance polyurethane elastomer is more reasonable, the product has higher quality and better comprehensive properties. The test date shows that the tensile strength is 3.50 to 5.80MPa, the elongation at break is more than 220 percent, the bond strength is more than 10.0MPa, the glass transition temperature is less than 60 DEG C below zero, the solidification shrinkage rate is less than 0.1 percent. The product is mainly applicable to aerospace industry.
Owner:SINOPEC LANZHOU GASOLINEEUM CHEM IND CORP

Preparation method of composite superhydrophobic coating possessing abrasion-resistance performance

The invention relates to a preparation method of a composite superhydrophobic coating possessing abrasion-resistance performance, which comprises the following steps: 1)performing prepolymerization on hydroxyl terminated polybutadiene and toluene diisocyanate at 70 DEG C for 1 hour to synthesize to obtain a polyurethane performed polymer, mixing the polyurethane performed polymer and acetone and diluting to a polyurethane performed polymer solution; 2)under the condition of 300-500r/minute of the stirring speed, adding the polyurethane performed polymer solution drop by drop in an acetone solution of ethene diamine, performing chain extension to obtain polyurethane sol; and 3)adding epoxy resin E-44, amino silicon oil and diethylenetriamine to polyurethane sol to form a spraying liquid, spraying the spraying liquid on a matrix, and forming a microscopic ordered dimpling structure which is the composite superhydrophobic coating on the surface after solidification. The method has the advantages of simple process and easy construction, the obtained composite superhydrophobic coating has excellent abrasion resisting performance after abrasion resistance test according to American material and test association standard (ASTM) D-968-05.
Owner:山东天汇防水股份有限公司
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