The invention relates to the field of
lithium ion batteries, in particular to copolymerized para-
aramid coating liquid as well as a preparation method and application thereof, by introducing a
naphthalene ring
structural unit and a stabilizer in a
polymerization process, the
solubility of para-
aramid is improved, self-aggregation among molecules is prevented, the stability of the
coating liquid is improved, and the
coating liquid can be stored for a long time. The
controllability of the
polymerization reaction can be remarkably improved by a
diamine monomer segmented feeding method, and the
thermal stability and
solubility of the copolymerized para-
aramid fiber are improved. The combination of the inorganic nanofibers and the para-aramid nanofibers is adopted as filler in the coating liquid, a
fiber network structure is provided, the
internal stress of the coating film during
phase change of the
polymerization stock solution is relieved, the problem of edge
curling of the diaphragm is avoided, and the problem that the bonding force is poor due to direct coating of the inorganic nanofibers and the para-aramid nanofibers is solved. After the copolymerized para-aramid
fiber coating layer is added, the
heat resistance of the diaphragm is obviously improved, the longitudinal
thermal shrinkage at 180 DEG C for 1 hour is less than or equal to 3%, the transverse
thermal shrinkage is less than or equal to 2%, and the safety of the
lithium battery is greatly improved.