The application relates to a fluorinated two-dimensional inorganic nanofiller reinforced PEO-based
solid-state
polymer electrolyte and a preparation method and application thereof, and comprises the following steps: S1, obtaining fluorinated two-dimensional inorganic nanofillers by treating two-dimensional
inorganic materials with a
mixed gas of
fluorine and
nitrogen; S2, dissolving
polyethylene oxide and a
lithium salt in a polar
solvent, then adding the fluorinated two-dimensional inorganic nanofillers obtained in the step S1, mixing, and obtaining a uniform mixed
polymer solution; and S3, pouring the mixed
polymer solution obtained in the step S2 on a
polytetrafluoroethylene mold,
vacuum drying, and obtaining the PEO-based
solid-state polymer
electrolyte. Compared with the prior art, the preparation process is simple and easy to operate, the
ionic conductivity of the polymer
electrolyte based on the fluorinated two-dimensional inorganic nanofillers can be improved, the electrochemical stability window can be widened, and the interface stability between the electrolyte and a
lithium metal electrode can be improved.