The invention relates to a method for separating and extracting
indium and
gallium from an
indium-
gallium solution. The method comprises the steps that (1) extraction is carried out, i.e., organic
phosphoric acid is adopted as an extraction agent, and diluents are added, so that an organic phase is obtained, and the organic phase is added to liquid to be extracted for extraction after pH value is adjusted; (2) reverse extraction of
indium is carried out, i.e., reverse extraction is conducted on the extracted phase in the step (1) with concentrated
hydrochloric acid, so that an indium-enriched aqueous phase is obtained; (3) reverse extraction of
gallium is carried out, i.e., reverse extraction is conducted on the organic phase subjected to reverse extraction in the step (2) with an
oxalic acid solution, so that a gallium-enriched aqueous phase is obtained; (4)
zinc or aluminum is added into the indium-enriched aqueous phase obtained in the step (2) to obtain indium through replacement, or alkaline substances are added to obtain indium
hydroxide sediment; (5) precipitants are added into the gallium-enriched water phase obtained in the step (3) to obtain
calcium oxalate,
filtration is carried out to remove
calcium oxalate, and replacement is carried out on liquid obtained after
filtration with
zinc or aluminum to obtain the simple substance gallium, or alkaline substances are added to obtain gallium
hydroxide sediment. According to the method, two elements are recovered by conducting extraction once and reverse extraction twice, separation is complete, the
recovery rate is high, operation is easy, and production cost is reduced.