The invention discloses a method for preparing a large-granule industrial-grade
urea phosphate product and a byproduct thereof through
continuous reaction crystallization of wet-process
phosphoric acid. The method comprises the steps: adding the wet-process
phosphoric acid,
urea and circulating
mother liquor into a first reaction crystallizer; feeding a reacted solution to a second-stage crystallizer, adding a
urea phosphate seed crystal, continuously outputting reaction obtained
slurry, carrying out
centrifugation and filtering, carrying out
drying so as to obtain industrial-grade
urea phosphate, and feeding filter liquor to a circulating
mother liquor tank for thorough
precipitation; cyclically outputting supernatant obtained through
precipitation to the first reaction crystallizer for acyclic reaction, and subjecting a suspension of
solid impurities to
centrifugation and filtering, so as to obtain second filter liquor and a second filtered
solid matter; adding
potassium sulfate into the second filter liquor, carrying out a reaction, and carrying out filtering, so as to obtain third filter liquor and a byproduct, i.e.,
potassium fluorosilicate; and mixing the third filter liquorand the second filtered
solid matter, carrying out concentrating, then, carrying out
spray drying so as to obtain a sulfenyl
nitrogen,
phosphorus and
potassium compounded
fertilizer, and carrying outcyclic
continuous production, thereby obtaining a
urea phosphate crystal. According to the method, the purity is high, the grain size is large, the distribution is uniform, the
crystal form is neat;and meanwhile, fluorosilicate and the sulfenyl
nitrogen,
phosphorus and potassium compounded
fertilizer can be obtained, and no waste gases, waste water and waste residues is discharged.