The invention discloses a preparation method of nylon 65 salt. Glutarate is dissolved in a
solvent, the mixture is heated to 30-50 DEG C, and a glutarate solution is prepared; hexamethylendiamine is dissolved in a
solvent, the mixture is heated to 30-50 DEG C, and a hexamethylendiamine solution is prepared; the hexamethylendiamine solution is dropwise added into the glutarate solution under
constant rate stirring at the temperature of 30-50 DEG C,
inert gas is introduced for protection, the pH value is monitored by a
pH meter in real time, the pH value is controlled to range from 7.20 to 7.90,and the reaction is carried out for 1.5 h to 5.0 h; after the material completely reacts, reduced pressure
distillation or direct suction
filtration is carried out, and then nylon 65 salt is dried ina
vacuum drying box for 24 h at the temperature of 60 DEG C; the dried nylon 65 salt is purified through a purification
solvent, the nylon 65 salt is dried, and the pure nylon 65 salt sample is obtained. The prepared nylon 65 salt is high in yield, the pH value is monitored by the
pH meter in real time in the reaction process, reaction monitoring is convenient, the
reaction conditions are moderate, and operation is easy.