This invention provides a sheet-like
sulfur-containing
carbon nitride / tubular
copper-doped
phosphorus-
nitride homo-
heterojunction, its preparation method, and its application. The preparation method is as follows: S1. Calcining trithiocyanate to obtain sheet-like
sulfur-containing
carbon nitride; dissolving
copper acetate and
melamine in water, then adding concentrated
phosphoric acid and stirring until homogeneous, and obtaining a tubular
copper-doped
phosphorus-
nitride precursor using a hydrothermal method; S2. Dispersing the tubular copper-doped
phosphorus-
nitride precursor and sheet-like
sulfur-containing
carbon nitride in
ethanol or an
ethanol-water solution, ultrasonicating, stirring,
drying, and then performing a second
calcination to obtain the sheet-like sulfur-containing carbon nitride / tubular copper-doped phosphorus-nitride homo-
heterojunction. The prepared sheet-like sulfur-containing carbon nitride / tubular copper-doped phosphorus-nitride homo-
heterojunction is sensitive to visible
light response, has high photocatalytic
hydrogen production activity, and the preparation method is simple, easy to operate, and has good reproducibility.