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392 results about "COBALTOUS NITRATE HEXAHYDRATE" patented technology

Cobalt Nitrate is the Inorganic compound with the formula CoNO32.xH2O. It is cobalt(II) salt. The most common form is the hexahydrate Co(NO3)2ยท6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.

Electrocatalyst with cobalt-based multi-stage nano-composite structure for oxygen production by electrolysis of water and preparation method of electrocatalyst

The invention provides an electrocatalyst with a cobalt-based multi-stage nano-composite structure for oxygen production by electrolysis of water and a preparation method of the electrocatalyst. The preparation method comprises the following steps: dissolving cobalt nitrate hexahydrate, urea and ammonium fluoride in deionized water to obtain a precursor solution; transferring the precursor solution into a hydrothermal reactor; adding carbon fiber paper; enabling basic cobalt carbonate nanowires to grow on the carbon fiber paper through solvothermal reaction; after finish of reaction, naturally cooling; then taking out a product; washing and drying to obtain a carbon fiver paper loaded basic cobalt carbonate nanowire composite structure; by taking powdered sulfur as the raw material, preparing a carbon fiber paper loaded cobalt sulfide nanowire composite structure through low-temperature sulfuration reaction under the condition of an inert gas; and finally, electroplating the surface of the carbon fiber paper loaded cobalt sulfide nanowire composite structure with a layer of cobalt hydroxide nanosheets by use of the electrochemical deposition method so as to obtain the electrocatalyst with the cobalt-based multi-stage nano-composite structure for oxygen production by electrolysis of water. As the sulfide and the hydroxide of transition metal cobalt are adopted as the catalyst, in comparison with noble metals, the cost of the catalyst is lowered.
Owner:JIANGSU UNIV

Preparation method of transition metal sulfide composite nanometer material

The invention discloses a preparation method of a transition metal sulfide composite nanometer material and belongs to the technical field of preparation of transition metal sulfides. The preparationmethod comprises the following steps of dissolving cobalt nitrate hexahydrate and 2-methylimidazole into methanol, performing stirring at a room temperature, performing still standing on an obtained solution for 12-36h at the room temperature, and preparing an ZIF-67 precursor; dissolving the cobalt nitrate hexahydrate and the ZIF-67 precursor into ethanol, performing dispersion, and performing stirring at the room temperature to form an Ni-Co-LDH intermediate; dispersing the intermediate in deionized water, adding a sulfur source and a molybdenum source, performing full stirring, transferringa mixture into a reaction kettle, adopting a hydrothermal method to perform stepwise temperature rising on the intermediate, then collecting a product through centrifugal washing, and drying at a certain temperature to obtain an NiCo2S4@MoS2 nanometer material. The preparation method provided by the invention is simple and green without pollution and is high in practical degree; and the obtainedNiCo2S4@MoS2 nanometer material can be directly used as an electrode material for a supercapacitor.
Owner:DALIAN UNIV OF TECH

Preparation method for metal organic framework-derived tricobalt tetroxide-modified titanium dioxide nanotube array

The invention discloses a preparation method for a metal organic framework-derived tricobalt tetroxide-modified titanium dioxide nanotube array. The method comprises the following steps: firstly performing pretreatment on a titanium sheet substrate material; performing electrochemical treatment on the treated titanium substrate material by using an ethylene glycol solution containing ammonium fluoride and water as an electrolyte, and performing calcination by using a muffle furnace to change a titanium dioxide crystal form; secondly, performing cobalt hydroxide electrodeposition by means of athree-electrode electrochemical workstation and by using cobalt nitrate hexahydrate as an electrolyte, a titanium dioxide nanotube array as a working electrode, a platinum sheet as a negative electrode and silver/silver chloride as a reference electrode; performing hydrothermal treatment on the titanium dioxide nanotube array to form ZIF-67 in situ; and finally, performing secondary calcination byusing a muffle furnace to obtain the ZIF-67-derived porous tricobalt tetroxide-modified titanium dioxide nanotube array. The method disclosed by the invention can effectively improve absorption capacity of TiO2 on visible light, promote separation of electron hole pairs, and improve photocatalytic degradation efficiency of organic pollutants.
Owner:SUZHOU UNIV

Preparation method of three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres

The invention relates to a preparation method of three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres, and relates to the technical field of multi-level structured nano-grade catalyst materials. First, nickel nitrate hexahydrate and cobalt nitrate hexahydrate are adopted as a nickel source and a cobalt source, a deionized water-isopropanol mixed phase with a proper proportion is adopted as a solvent, methanol is adopted as a reactant, and no additional base precipitating agent is adopted; a three-dimensional flower-shaped nano-sheet microsphere precursor is prepared in a Ni<2+>-Co<2+>-NH3-NH4<+>-SG<n->-H2O-IPA-CH3OH system (SG<n-> is CO3<2-> or HCOO<->); the temperature is increased to 300-400 DEG C in an air atmosphere with a speed of 1 DEG C/min, and the precursor is calcined for 2-3h, such that the three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres are obtained. According to the invention, co-precipitation of the formulated cobalt and nickel in the raw materials is realized. The prepared three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres are spinel cubic phases with high purity, and are formed by ultrathin nano-sheet self-assembly. The microspheres comprise rich mesopores, and have a large specific surface area. The method has the advantages of simple operation, appropriate conditions and easy control.
Owner:BEIJING UNIV OF CHEM TECH

Metal oxide-loaded molecular sieve catalyst and preparation method thereof

A metal oxide-loaded molecular sieve catalyst comprises pure cryptomelane type manganese dioxide and transition metal. A method for preparing the molecular sieve catalyst comprises the following steps: 1, preparing solution of potassium permanganate; 2, preparing solution of manganese acetate; 3, adding the solution obtained by the step one into a three-neck flask, and heating, condensing and refluxing the solution; 4, adding the solution obtained by the step two into the three-neck flask of the step three, condensing and refluxing the solution, filtering and drying the obtained black pasty sediment, and roasting the sediment to obtain an octahedral manganese oxide molecular sieve catalyst (OMS-2) solid; 5, adding cerium ammonium nitrate, cobalt nitrate hexahydrate, copper nitrate trihydrate, ferric nitrate nonahydrate or yttrium nitrate into deionized water to form solution; and 6, mixing the solid taken from the step four and the solution in the step five, soaking cerium on the octahedral manganese oxide molecular sieve catalyst (OMS-2) solid, and drying and roasting the obtained solid to obtain the metal oxide-loaded molecular sieve catalyst. The metal oxide-loaded molecular sieve catalyst has the characteristics of high purification efficiency, low price and good thermal stability.
Owner:TSINGHUA UNIV

Composite hydrogen evolution electro-catalysis material and preparation method

The invention relates to a molybdenum disulfide-cobalt disulfide/graphene composite hydrogen evolution electro-catalysis material and a preparation method and belongs to the field of electro-catalysishydrogen evolution. The molybdenum disulfide-cobalt disulfide/graphene composite hydrogen evolution electro-catalysis material is mainly prepared through the following steps that firstly, an advancedHummers method is adopted to prepare graphene oxide; then with sodium molybdate dihydrate, cobalt nitrate hexahydrate, thiourea, graphene oxide and deionized water as raw material, and through a one-step solvent thermal reaction method under 200 DEG C, the ternary molybdenum disulfide-cobalt disulfide/graphene composite hydrogen evolution electro-catalysis material is prepared; and the electro-catalysis hydrogen evolution performance is analyzed. The preparation method has the beneficial effects of being easy to operate, low in energy consumption and the like; transition metal of cobalt and molybdenum for use is low in price, and it is hopeful that the material is applied in industrial production; and besides, a electro-catalysis hydrogen evolution performance test shows that the preparedmolybdenum disulfide-cobalt disulfide/graphene composite hydrogen evolution electro-catalysis material is large in electronic transmission rate and good in hydrogen evolution performance.
Owner:JIANGSU UNIV

Preparation method of three-dimensional mesoporous NiCo2O4/nitrogen-doped graphene composite electrode material

The invention provides a preparation method of a three-dimensional mesoporous NiCo2O4/nitrogen-doped graphene composite electrode material. The preparation method comprises the following steps: step 1, implementing ultrasonic dispersion on graphene oxide in an acetonitrile system to obtain a uniform graphene oxide solution A; step 2, transferring the solution A to a polytetrafluoroethylene hydrothermal reactor to implement constant-temperature thermal reaction, and completing the reaction to obtain mixed liquid B; step 3, implementing extraction filtration, washing and drying on the mixed liquid B to obtain a product C; step 4, implementing uniform ultrasonic dispersion on the product C, cobalt nitrate hexahydrate, nickel nitrate hexahydrate and hexamethylenetetramine to obtain mixed liquid D; step 5, transferring the mixed liquid D to the polytetrafluoroethylene hydrothermal reactor to implement constant-temperature thermal reaction, and filtering and washing the liquid to obtain a nickel cobaltate precursor E; and step 6, putting the precursor E into a tubular furnace, and implementing calcination at an air atmosphere to obtain a reaction product namely the three-dimensional mesoporous NiCo2O4/nitrogen-doped graphene composite electrode material. The preparation method provided by the invention is mild in reaction condition, easy to control, low in cost, and simple and convenient in process and procedure.
Owner:JIANGSU UNIV

Preparation method of sea-urchin-shaped cobalt acid copper nanometer material of nickel foam load

The invention discloses the preparation method of the sea-urchin-shaped cobalt acid copper nanometer material of a nickel foam load. In the method, cobalt nitrate hexahydrate, copper acetate monohydrate, ammonium fluoride and urea are used as raw materials, absolute ethyl alcohol and deionized water are used as a solvent, and through hydrothermal growth and a high temperature calcination method, the cobalt acid copper nanometer material possessing a sea urchin structure is prepared. By using the sea-urchin-shaped cobalt acid copper nanometer material of the nickel foam load prepared through using the method of the invention, especially when a calcination temperature is about 550 degree centigrade, the sea urchin shape of the acquired sea-urchin-shaped cobalt acid copper nanometer materialof the nickel foam load is uniform and ordered, and excellent electrochemistry performance and good multiplying power performance are achieved. The preparation technology is simple, the method is energy-saving and environmental-protection, the raw materials are cheap, time consuming is less and the method is easy for batch production. The sea-urchin-shaped cobalt acid copper nanometer material isapplied to a lithium ion battery cathode material and has the excellent electrochemistry performance.
Owner:SOUTH CHINA NORMAL UNIVERSITY

High-efficiency moisture-proof ozonolysis catalyst and preparation method thereof

The invention discloses a high-efficiency moisture-proof ozonolysis catalyst and a preparation method thereof, belonging to the technical field of ozone purification catalysts. According to the high-efficiency moisture-proof ozonolysis catalyst disclosed by the invention, the oxides of manganese, copper, nickel and cobalt are taken as active components; the preparation method of the high-efficiency moisture-proof ozonolysis catalyst is a sol-gel method; in the preparation process, manganese nitrate tetrahydrate, copper nitrate trihydrate, nickel nitrate hexahydrate and cobalt nitrate hexahydrate are dissolved in deionized water to obtain a nitrate solution; the nitrate solution is slowly added in a mixed solution of citric acid and a cationic surface active agent; after the pH value of the mixed solution is adjusted with ammonium hydroxide, constant temperature stirring is performed to obtain gel; and after the gel is dried, calcination is performed to obtain the ozonolysis catalyst. The preparation method disclosed by the invention is simple and low in costs, solves the problem that the ozonolysis catalyst is relatively poor in moisture-proof performance, and meanwhile, improves the ozonolysis efficiency; and the ozonolysis catalyst is long in service life, and the ozonolysis efficiency is not lowered when the ozonolysis catalyst is continuously used for a month.
Owner:ACAD OF ENVIRONMENTAL PLANNING & DESIGN GRP CO LTD NANJING UNIV

Low overpotential electrocatalyst for producing hydrogen by efficient water splitting and preparation method of electrocatalyst

The invention provides a low overpotential electrocatalyst for producing hydrogen by efficient water splitting and a preparation method of the electrocatalyst, and belongs to the technical field of catalyst preparation. The low overpotential electrocatalyst is prepared by in-situ growth of Co9Se8 on foamed nickel. The low overpotential electrocatalyst is prepared by one of cobalt nitrate hexahydrate, cobalt chloride, cobalt acetate or cobalt sulfate and one of sodium selenite pentahydrate, potassium selenite or seleninic acid in an organic amine environment in which the foamed nickel serves as a catalyst. The foamed nickel can serve as both a carrier and the catalyst of a synthetic reaction. The overpotential of the electrocatalyst is only -284mV when the electric current density is 80 mA / cm<-2> and is increased by more than 46.5% relative to that of pure foamed nickel with the overpotential of -530 mV when the electric current density is 80 mA / cm<-2>, and the electrocatalyst is a relatively low overpotential electrocatalyst in non noble metal electrocatalysts. The electrocatalyst is one of advanced technical means for the sustainable production of hydrogen energy, has good industrial application prospects and can be used to relieve an increasingly intense global energy supply pattern at present.
Owner:JILIN UNIV

Iron/cobalt duplex-metal organic framework material as well as preparation method and application thereof

The invention relates to an iron / cobalt duplex-metal organic framework material as well as a preparation method and application thereof. The preparation method comprises the steps: dissolving cobalt nitrate hexahydrate, iron dichloride tetrahydrate and terephthalic acid into N,N dimethyl formamide to obtain a precursor solution; performing hydrothermal reaction on the precursor solution for 14 to27 h under the temperature of 110 to 170 DEG C; cooling, washing and drying to obtain the iron / cobalt duplex-metal organic framework material. Duplex transition metal coordination sites which are highly dispersed in the prepared iron / cobalt duplex-metal organic framework material disclosed by the invention can enhance effective contact between the iron / cobalt duplex-metal organic framework material and persulfate and can efficiently catalyze the persulfate to generate sulfate radicals; thus, persistent organic pollutants in wastewater can be removed. The iron / cobalt duplex-metal organic framework material is suitable for treating varieties of organic wastewater and has the advantages of high activity, small use amount, wide application pH range, good durability, convenience in operation and environmental friendliness and wide prospect in treating toxic and harmful organic wastewater which is difficult to biodegrade.
Owner:HANGZHOU DIANZI UNIV

Cobalt-based MOFs material, and preparation method and application thereof

The invention discloses a cobalt-based MOFs material. The cobalt-based MOFs material is formed by cobalt-nitrate hexahydrate which is reacted with terephthalic acid through a hydrothermal method, andthen is washed and dried through N, N-dimethyl formamide and an absolute ethyl alcohol solvent. A preparation method comprises the following steps: firstly, adding cobalt-nitrate hexahydrate in absolute ethyl alcohol, and performing magnetic stirring, so as to obtain a clear cobalt nitrate solution, adding terephthalic acid in N, N-dimethyl formamide, and performing magnetic stirring, so as to obtain clear a terephthalic acid solution, and performing mixed ultrasonic treatment on the two solutions; secondly, loading the solution subjected to mixed ultrasonic treatment into a reaction kettle, and arranging the reaction kettle into an oven, ensuring that the solution is reacted under a certain condition, and filtering, washing and drying a reaction product in certain condition after the reaction, so as to obtain the cobalt-based MOFs material. When the material is applied to the catalysis of hydrolysis of sodium borohydride, the hydrolysis speed reaches 1700 to 2400 mL min-1g-1, and thecatalytic performance keeps 47 to 50 percent of the original hydrogen yield after circulation. The material has excellent catalytic performance, and has a wide application prospect in the field of thepreparation of new energy resources.
Owner:GUILIN UNIV OF ELECTRONIC TECH

Method for manufacturing graphene/two-dimensional Co-Zn dual-core metal frame structure composite material

The invention discloses a method for manufacturing a graphene/two-dimensional Co-Zn dual-core metal frame structure composite material. The method comprises: adding an aqueous solution of zinc nitratehexahydrate to a 2-methylimidazole aqueous solution, mixing uniformly, stirring, and performing water centrifugal washing, and then freezing and drying to obtain a precursor two-dimensional organometallic frame structure material ZIF-8; then dispersing the precursor two-dimensional organometallic frame structure material ZIF-8 into an aqueous solution of graphene oxide, stirring at room temperature to make the precursor two-dimensional organometallic frame structure material ZIF-8 uniformly dispersed, adding cobalt nitrate hexahydrate, and then continuing to stir and performing centrifugal washing to obtain an intermediate product; performing low temperature pyrolysis on the intermediate product under a nitrogen atmosphere, to obtain a target product graphene/two-dimensional Co-Zn dual-core metal frame structure composite material. The composite material prepared by the method has uniform morphology, stable structure and good toughness, and the process is green and energy saving, andis efficient and simple, and easy for scale production.
Owner:HENAN NORMAL UNIV
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