The invention provides a Fe / Cu-BTC-BA catalyst as well as a preparation method and application thereof, and relates to the technical field of
metal organic framework materials. The preparation method comprises the following steps: mixing an
iron source, a
copper source,
trimesic acid,
benzoic acid and hexadecyl trimethyl
ammonium bromide with a
solvent, carrying out
solvothermal reaction at 120-140 DEG C for 20-28 hours, and filtering, washing and
drying to obtain the target catalyst. Fe-Cu double active sites are constructed and are combined with double ligands to induce Cu < 2 + > to be converted into Cu < + >, so that the Lewis acidity and
hydrogen sulfide adsorption activation capability are enhanced, the skeleton stability is improved, and meanwhile, the pore structure is optimized. The catalyst has the advantages of high specific surface area, highest
sulfur capacity of 7.8%, high desulfurization rate and stable structure, and is suitable for catalytic desulfurization of
sulfur-containing gas.