The invention discloses a preparation method of a porous
aluminum phosphate block. According to the preparation method, aluminum
chloride hexahydrate is taken as an aluminum source,
phosphoric acid is taken as a
phosphorus source, a mixture of deionized water and absolute
methanol is taken as a
solvent, propylene
epoxide is taken as a gel accelerator, and polyoxyethylene is taken as a phase separation inductive agent; the following steps are sequentially performed: 1), aluminum
chloride hexahydrate and polyoxyethylene are put in a reaction flask, deionized water, absolute
methanol and
phosphoric acid are doped, and stirring is performed until polyoxyethylene is dissolved completely; 2), under the condition of ice bath, propylene
epoxide is doped into a solution obtained in step 1), stirring is continuously performed until propylene
epoxide is dissolved completely; 3), the reaction flask is sealed and aged, then a lid is opened, and
drying is performed; and 4), obtained xerogel is processed for 1.5-2.5 hours at the temperature of 1,050-1,150 DEG C so as to obtain the porous
aluminum phosphate block. The porous
aluminum phosphate block can be directly applied to the fields of
catalysis, separation, absorption, extraction, degradation, curing and the like.