The invention discloses a preparation method of a surface die pressing film of a PVC-based stone-plastic composite board. The preparation method comprises the steps that the surface of the PVC-based stone-plastic composite board is subjected to activating treatment, specifically, activated putty is prepared, the surface of the base material is crudely roughened, the activated putty is applied, curing is carried out, and the surface of the base material is finely roughened; PMMA slurry is prepared; and film coating and forming is carried out on the surface of the PVC-based stone-plastic composite board, specifically, the board is put in a die, cold-pressing shaping, tightening by a clamp, low-temperature curing, high-temperature treatment and cooling die-release are carried out, and thus the PVC-based stone-plastic composite board with the surface coated with the PMMA film is obtained. According to the PVC-based stone-plastic composite board with the surface coated with the PMMA film, which is prepared by the preparation method provided by the invention, the problems that in a traditional situation of producing floors with surface printing and surface film-sticking technologies, theinvestment of related production lines and equipment is large, and the production cost is high can be avoided; the board provided by the invention can partially replace composite floors, stone materials, acrylic face plates, curtain wall plates and the like, which are popular in the market currently; and a new path is provided for high value-added utilization of waste.