The application discloses a kind of based on liquid
tungsten oxide carbon thermal reduction ultra-coarse
tungsten carbide powder preparation method, belong to
powder metallurgy technical field.The method includes:
tungsten oxide is mixed with
carbon black, and mixed
powder is obtained;The mixed powder is placed in
inert atmosphere and is treated by three-stage heating, so that the
tungsten oxide is dehydrated, pre-reduction is experienced, and is melted into
liquid state, and carbon thermal reduction reaction is carried out with the
carbon black;After reaction, in-situ weak
oxygen decarburization treatment is carried out, and the ultra-coarse
tungsten carbide powder is obtained;The three-stage heating is: first stage is heated to 280-320 DEG C and is dehydrated, second stage is heated to 1150-1200 DEG C and is pre-reduced, and third stage is heated to 1250-1600 DEG C, so that
tungsten oxide is in liquid melt state, and carbon thermal reduction reaction occurs with
carbon black.The method provided by the application has the advantages of simple process, wide
raw material adaptability, high product purity, uniform grain and the like.