83results about How to "Play a role in crosslinking" patented technology

The powerful adhesive includes neoprene, grafting monomer, thickener, dispersant, adhesion promoter, catalyst, antioxidant, solvent, stuffing, etc. The present invention also discloses the preparation process of the adhesive, and the preparation includes introducing grafting monomer to neoprene molecule chain to raise the adhesion strength, selecting proper adhesion promoting resin to increase the initial adhesion force, and adopting mixed solvent to form high adhering performance. The adhesive has high solid content and excellent environment protecting performance, and has also excellent antiageing performance, high resistance to heat, oil, chemical and corrosion, high weather resistance, good mildew-proof performance, antibiotic performance, etc. and may be used for adhering timber, concrete, rubber, metal, gypsum board, brick and other building material.

The present invention provides a preparation method for aqueous polyurethane. The method comprises the following steps: mixing aliphatic diisocyanate, an aliphatic polyol, dimethylol propionic acid and a catalyst, and carrying out a reaction to obtain a prepolymer; adding a neutralizing agent to the prepolymer, and carrying out a stirring reaction to obtain an intermediate product; adding water and a chain extender to the intermediate product, stirring and dispersing to obtain the aqueous polyurethane, wherein the chain extender is polyoxyethylene polyamine or polyoxypropylene polyamine. The invention further provides the aqueous polyurethane prepared by the method. According to the present invention, the bulk polymerization method is adopted, the use of the organic solvent is not required, and no environmental pollution is generated; the polyoxyethylene polyamine or the polyoxypropylene polyamine is adopted as the chain extender, and is used for emulsion chain extending, such that the obtained polyurethane emulsion has good film-forming flexibility, the mechanical property of the obtained polyurethane can not be reduced, the large R value is not required, and the final produced polyurethane film is soft.

The invention relates to the three dimensional rapid moulding photosensitive resin field, and discloses a photosensitivity siloxane and hyperbranched polyether polyol-containing photosensitive resin composition. The composition is suitable for a light-cured three dimensional rapid moulding technology, and comprises A)a low-viscosity photosensitivity group (methyl) acrylate group-containig siloxane with usage amount being 0.1-30wt%; B) hyperbranched polyether polyol with number-average molecular weight being 400-20000g / mol and usage amount being 0.1-50wt%; C)an epoxide group-containing cation light-cured compound with usage amount being 5-70 wt%; D)an unsaturated bond function group-containing free radical light-cured compound usage amount being 2-30 wt%; E)a cation photoinitiator usage amount being 1-10 wt%; F)a free radical photoinitiator usage amount being 1-10 wt%; G)a filling material usage amount being 1-20wt%; H)other auxiliary materials usage amount being 0.1-5wt%. The photosensitive resin composition has good mechanics, calorifics performance and solidification performance of a solidification object after laser three dimensional rapid moulding.

The invention belongs to the field of organic / inorganic nano composite hydrogel, and particularly discloses a preparation method of polymer hydrogel based on cross-linking of a two-dimensional titanium carbide layered compound. The method comprises the step of: with Ti3C2 nanosheets as a cross-linking agent and acrylic compounds and / or acrylamide compounds as monomers, performing a polymerizationreaction so as to obtain the polymer hydrogel. The invention also discloses the polymer hydrogel prepared by using the preparation method and application of the polymer hydrogel as a thermo-sensitivephase-change and / or near-infrared photothermal conversion material. According to the preparation method, the obtained polymer network structure is in situ doped with the Ti3C2 nanosheets which participate in the polymerization reaction through a physical and chemical crosslinking mode, not only can novel photoelectric characteristics be given to the polymer hydrogel, but also excellent mechanicalproperties, such as self-healing performance and high toughness, can be achieved.

The invention discloses a preparation method of a moisture-absorbing polyester fabric. The preparation method comprises the following steps of (1) preparing an alkaline treatment solution, impregnating polyester fibers into a solution, washing and drying; (2) preparing a sucrose fatty acid ester solution, impregnating the polyester fibers into the sucrose fatty acid ester solution, washing, and drying; (3) selecting a certain mass of raw silk, and preparing into 2 2 to 5% sericin solution; (4) preparing the following solutions comprising 8 to 12wt% of epichlorohydrin solution, 1 to 5wt% of tetrabutylammonium bromide solution, 1 to 3wt% of coupling agent solution, 30 to 50wt% of JCH solution with concentration of 0.3%, and 40 to 50wt% of sericin solution; (5) impregnating the polyester fibers into the solutions in step (4), washing, and drying; (6) performing secondary impregnating on the treated polyester fibers in step (5), washing, and drying; (7) preparing the polyester fibers intothe fabric. The preparation method has the advantage that the outer surface of the polyester fiber is coated with one layer of sericin, and the sericin has good moisture absorbing property, so that the defect of poor moisture absorbing property in the polyester fiber is overcome.

The invention relates to a polyurethane acrylate adhesive containing ionic groups and a preparation method thereof. The adhesive comprises the following components in part by weight: 45 to 75 parts of macromolecular polyol, 1.5 to 3 parts of carboxylic acid compound or sulfonate, 15 to 30 parts of diisocyanate, 0.01 to 0.06 part of catalyst, 8 to 21 parts of monohydric alcohol containing acrylategroup and 0.01 to 0.06 part of free radical polymerization inhibitor. The method comprises the following steps of: adding the carboxylic acid compound or the sulfonate into the macromolecular polyol,adding the diisocyanate and the catalyst into the dehydrated mixture, heating the mixture, then adding the monohydric alcohol containing the acrylate group and the free radical polymerization inhibitor into the mixture, reacting the mixture to obtain a polyurethane acrylate polymer at a controlled temperature, and adding a mixture of diluent and initiator into the polymer to obtain a product. Compared with the prior art, because the adhesive contains the ionic groups, the adhesive has higher strength and toughness; and the multi-functionality macromolecular polyol also increases the mechanical strength of the adhesive.

The invention relates to an electrochemical L-lysine sensor based on a graphene material and a preparation method thereof. The preparation method comprises the following steps: modifying a glassy carbon electrode with L-lysine oxidase, with the graphene material as a sensitizing material; and separately arranging the modified glassy carbon electrode used as a working electrode, a saturated calomelelectrode used as a reference electrode and a platinum electrode used as an auxiliary electrode in an electrolytic bath to form a three-electrode system so as to prepare the electrochemical L-lysinesensor. The invention also relates to application of the electrochemical L-lysine sensor based on the graphene material to detection of L-lysine in food or medicines. The electrochemical L-lysine sensor based on the graphene material has the advantages of simple and rapid detection, high sensitivity and low cost and can achieve the purpose of high-selectivity identification and detection of L-lysine.

The invention relates to a surface sizing agent, which contains a polymer of cationic starch grafted monomers and succinylated chitosan sodium, wherein the cationic starch grafted monomers comprise three monomers such as a hard monomer, a soft monomer and a cross-linking monomer, the hard monomer is a mixture comprising one or a plurality of materials selected from styrene, methyl styrene, methyl methacrylate and methyl acrylate, the soft monomer is a mixture comprising one or a plurality of materials selected from n-butyl acrylate, tert-butyl acrylate and octadecyl acrylate, and the cross-linking monomer is a mixture comprising one or two materials selected from 2-hydroxyethyl acrylate and methylol acrylamide. The present invention further provides a preparation method for the surface sizing agent, a sizing liquid containing the surface sizing agent, and sizing paper prepared by applying the sizing liquid containing the surface sizing agent to carry out sizing. The surface sizing agent has characteristics of low price, green environmental protection and good use effect.

The invention discloses a highly skin friendly bacteriostatic fabric and a preparation method thereof. The bacteriostatic fabric includes a modified base-layer fabric and a waterproof layer laid on the modified base-layer fabric; the modified base-layer fabric is obtained by spinning and forming with modified antibacterial fiber as a raw material, and the waterproof layer is prepared by processinga homogeneous mixture of modified waterproof fiber and hot melting fiber; the modified base-layer fabric has good skin friendliness and antibacterial properties, the waterproof layer laid on the modified base-layer fabric after forming by an air-laid technology is obtained by adopting the skin friendly fabric as a raw material to be subjected to water modification of surface water, on the one hand, compared with a textile fabric, pores of the waterproof layer formed by the air-laid technology are smaller, water and wind resistant effects of the fabric are advantageously improved, and on the other hand, the prepared modified waterproof fiber taking the skin friendly fabric as the raw material can make the fabric still maintain good air permeability.

The invention discloses a production method of polyester fabric with hygroscopicity. The method comprises the following steps that (1) alkaline treatment solution is prepared, polyester fibers are immersed in the solution, and washing and drying are conducted; (2) sucrose fatty acid ester solution is prepared, and the polyester fibers are immersed in the sucrose fatty acid ester solution, then washed and dried; (3) a certain mass of raw silk is taken and prepared into 2-5% of sericin solution; (4) 8-12 wt% of epichlorohydrin, 1-5 wt% of tetrabutylammonium bromide, 1-3 wt% of coupling agent, 30-50 wt% of JCH solution with the concentration 0.3% and 40-50 wt% of sericin solution are prepared; (5) the polyester fibers are immersed in the solutions prepared in the step (4), then washed and dried; (6) secondary immersion is conducted on the polyester fibers treated through the step (5), and then washing and drying are conducted; (7) the polyester fibers are made into fabric. According to the method, the outer surface of the polyester fibers is coated with a layer of sericin, and sericin has excellent hygroscopicity, so that the defect of poor hygroscopicity of polyester fibers is overcome.

The present invention relates to: a method for manufacturing a crumpled graphene composite. The method comprises a step of spraying, drying, and thermally treating a solution containing graphene oxideand a conductive material; a graphene composite manufactured thereby; and a supercapacitor to which an electrode including the same is applied.

The invention relates to gelatin bacteriostatic fiber modified by trivalent cerium and a preparation method and application thereof. The gelatin bacteriostatic fiber is prepared by a method of blending trivalent cerium solution and gelatin solution, performing solution spinning and heating and drying in vacuum. The gelatin bacteriostatic fiber is characterized in that: due to the adoption of the trivalent cerium, the gelatin bacteriostatic fiber not only has the effect of antibacterium and anticoagulation but also has improved strength and water resistance. As the fiber has high mechanical property, biocompatibility and the effect of antibacterium and anticoagulation, the fiber has a wide application prospect in the field of medicament, spinning and the like.

The present invention is one kind of filming resin containing silicon couplant and one kind of antireflecting coating composition prepared with the resin and used in microelectronic photoetching process adopting KrF laser, ArF laser or F2 laser as exposure light source. The filming resin consists of mainly silicon-containing acrylate couplant monomer in 1-40 weight portions and acrylate couplant monomer containing light absorbing group in 1-40 20-80 weight portions, and is prepared through copolymerization in solution in the presence one free radical initiator and corresponding pre-treatment. The antireflecting coating liquid is compounded with the filming resin, stabilizer, leveling agent and small amount of additive in solvent. The silicon-containing acrylate couplant participate in the copolymerization and cross-linking reaction and may result in good photoetched pattern.

The invention discloses a graphene regenerated rubber-plastic foamed insole and a preparation method thereof. The foamed insole is prepared by the following raw materials in parts by weight: 17-22 parts of an ethylene-vinyl acetate copolymer, 35-42 parts of an ethylene-vinyl acetate copolymer offcut grinding powder, 5-7 parts of ethylene propylene diene monomer rubber, 3-6 parts of oxidized polyethylene, 3.5-5.5 parts of graphene, 1-1.5 parts of carboxylated graphene, 30-37 parts of a thermoplastic polyester elastomer, 10-14 parts of a polyester-polyether block copolymer, 2-4 parts of fluorinated polyethylene, 1.2-2.3 parts of a foaming agent, 0.7-1.1 parts of a bridging agent, 2.5-4.5 parts of aluminum silicate fiber tubes, 2.5-4 parts of an antioxidant, and 3-4.5 parts of zinc stearate.The graphene regenerated rubber-plastic foamed insole has good mechanical properties such as high tensile strength and the like, the hardness is moderate, the air permeability is good, the service life as an insole material is long, the foamed insole is not easy to have excessive deformation, and the comfort degree is high. The recycling of EVA is realized, the utilization rate of EVA is improved,the raw material cost is reduced, and thus the foamed insole is more environment-friendly.

The invention relates to the technical field of epoxy self-adhesive paint, in particular to insulating waterborne epoxy self-adhesive paint and a preparation method thereof. The insulating water-based epoxy self-adhesive paint is prepared from the following raw materials: epoxy resin, a cosolvent, spherical organic silicon resin, a water-based coupling agent, an emulsifier, water, a latent curing agent, a leveling agent, a wetting agent and an antifoaming agent. The self-adhesive paint has the excellent effects of high temperature resistance, smoothness, low specific gravity, water resistance, salt spray resistance and insulation. The preparation method comprises the following steps: adding the spherical organic silicon resin and the coupling agent into water, heating, and carrying out heat preservation reaction to obtain a modifier; dissolving epoxy resin in a cosolvent, heating, adding the modifier and the emulsifier, uniformly stirring, and dropwise adding residual water until the viscosity is reduced in a cliff manner; finally, adding a latent curing agent, a leveling agent, a wetting agent and an antifoaming agent, keeping the temperature, and performing uniform dispersing to obtain a finished product. The preparation method is simple to operate and convenient for batch production.

The invention provides a high-bending-resistance PU (polyurethane) shoe material which is prepared from the following components in parts by weight: 40-60 parts of polyether glycol, 5-15 parts of chain extender, 25-35 parts of isocyanate, 2-6 parts of nano montmorillonite, 0.3-1 part of coupling agent, 0.1-0.5 part of catalyst, 0.1-0.5 part of antioxidant and 0.5-2 parts of water. The invention also provides a manufacturing method of the high-bending-resistance PU shoe material. The PU shoe material provided by the invention has excellent bending resistance.

The invention discloses a convex hot-melt marking line. The convex hot-melt marking line is prepared from the following raw materials in parts by weight: 10-15 parts of modified C5 petroleum resin, 5-10 parts of polyurethane, 30-45 parts of glass beads, 30-40 parts of nano silicon dioxide, 10-15 parts of calcium carbonate, 10-15 parts of titanium dioxide, 3-5 parts of polypropylene wax, 2-3 partsof stearic acid, 1-2 parts of glyceryl stearate, 1-3 parts of a flatting agent and 2-5 parts of a plasticizer. The invention also discloses a preparation method of the convex hot melt marking line. The modified C5 petroleum resin not only has high polarity, and also endows the convex hot-melt marking line with good corrosion resistance and film forming performance; the calcium carbonate and the titanium dioxide are added in a preparation process, so that the reinforcing, anti-aging and filling effects can be exerted; wear resistance of the marking line can be enhanced through addition of the polyurethane and the nano silicon dioxide; and the modified C5 petroleum resin has high polarity, and then can be better blended with polyurethane, so that stability of the system is guaranteed.

The invention discloses a bituminous mixture for a heavy-load transportation road surface and a preparation technology of the bituminous mixture. The problems that under the current market condition,polytetrafluoroethylene fibers are used for modifying bituminous, but the polytetrafluoroethylene fibers have the defects that the abrasion-resistant property is poor, the hardness is low, the dimensional stability is poor and the like, and the abrasion resistance and the mechanical properties of the bituminous mixture are greatly influenced are solved; and aiming at the problems, nano-silicon dioxide is added to the bituminous, the polytetrafluoroethylene fibers are filled with the nano-silicon dioxide, the thermal conducting property of polytetrafluoroethylene fibers is appropriately improved, the creep resisting property of the polytetrafluoroethylene fibers is improved, large-area strip-shaped abrasive dust is prevented from being generated in the friction process of the bituminous mixture, and the abrasion resistance of the polytetrafluoroethylene fibers is improved. According to the bituminous mixture for the heavy-load transportation road surface and the preparation technology of the bituminous mixture, appropriate proportion is obtained through multiple experiments, the technology is reasonable, the mechanical strength and the abrasion resistance property of the bituminousmixture are effectively improved, the compatibility between the bituminous and components is further improved, and the bituminous mixture is more stable and is high in practicability.

The invention discloses a preparation method of a light modulation terahertz absorption device with an all-carbon structure, and the method comprises the steps: obtaining an independent support graphene nano material through simple chemical assembly and reduction and molecular crystal auxiliary transfer, and obtaining a defect-controllable graphene film structure through the regulation and controlof sintering temperature and time. The film has good terahertz permeability or shielding property. The thin-film polyimides of different structures are assembled layer by layer to form a sandwich structure, the sandwich structure is placed under terahertz light, the terahertz transmission spectrum peak position changes along with increase of the concentration of molecules dropwise added to the surface, so that a terahertz molecular detection device can be prepared and used for detecting molecular residues. And meanwhile, the double graphene nano-film layers can be subjected to optical regulation and control and can be used for detecting the change of optical intensity. Besides, two etching methods are combined, the specific surface area is increased at different scales, the change of theelectrical property of the material is greater and the change of a terahertz signal is also greater under the dropwise addition of the same molecular content detection.

The invention discloses a preparation method of an organosilicon conductive adhesive containing nanorod-shaped zinc oxide, which comprises the following steps: preparing a modified rod-shaped zinc oxide dispersion liquid, adding an organic monomer into the modified rod-shaped zinc oxide dispersion liquid to carry out polymerization reaction, and adding a conductive polymer monomer to carry out polymerization reaction, thereby obtaining the organosilicon conductive adhesive containing nanorod-shaped zinc oxide. The organosilicon conductive adhesive has the advantages of excellent conductivity,excellent mechanical properties and low production cost.

The invention discloses a preparation method of a marine organism nano antibacterial gel-liquid adhesive bandage. The marine organism resource such as chitin, sodium alginate, and the like is utilized to prepare supermolecular gel; through technologies such as ion bonding reactions, silver ion complexing reactions, nano silver reactions, embedding, and the like, the marine organism nano antibacterial gel-liquid adhesive bandage is produced finally; and the adhesive bandage has the advantages that the adhesive bandage has a supermolecular network structure, can stop bleeding quickly, has a good antibacterial and inflammation-resistant property, and can be used in battlefield. The obtained adhesive bandage is in a liquid state, has the functions of stopping bleeding, relieving itch, repairing skin, promoting healing, and reducing scars, and has the characteristics of quick film forming property, easiness for removing, and odorless property. The adhesive bandage can be used to stop bleeding and kill bacteria on skin wounds, can assist the treatment of skin itch, beriberi, and eczema, and is capable of assisting the treatment of skin wounds of scald and burn.

The invention discloses a weather-resistant wire and cable material. The material is characterized by being prepared from following raw materials in parts by weight: 70-80 parts of perfluorotriazine rubber, 15-25 parts of epichlorohydrin rubber, 20-30 parts of benzotriazole-1-carbothioic acid allyl amide / 2,4-diamino-6-vinyl-S-triazine / titanium triisopropanol methacrylate / 4-hydroxybutyl vinyl ethercopolymer, 5 to 10 parts of industrial solid waste, 5 to 10 parts of volcanic ash, 2 to 5 parts of epoxy asphalt, and 3 to 6 parts of a vulcanizing agent. The invention also discloses a production method of the weather-resistant wire and cable material. The weather-resistant wire and cable material is excellent in comprehensive performance, excellent in mechanical property, weather resistance andflame resistance, good in wear resistance, aging resistance and heat resistance, high in use safety and long in service life.

The invention belongs to the field of chemical modification of a natural high polymer material, and relates to a preparation method of high-viscosity pelletizing sodium carboxymethylcellulose. The sodium carboxymethylcellulose is industrially produced by a kneading method; the obtained sodium carboxymethylcellulose product is added to a steam stripper to carry out partial hydrolyzing in the presence of inert gases after alkalization and etherification reaction, so that the particle morphology of the product can be well controlled in a crushing process so as to play a cross-linking role by adding aluminum chloride, and the granular sodium carboxymethylcellulose with high viscosity is finally obtained. The method disclosed by the invention is simple in technical process of production, short in reaction period, less in equipment investment, low in material consumption, small in dust pollution in the entire process, and environmentally-friendly, and the body health hazard to an operator is reduced to the minimal extent.

The invention belongs to the technical field of binders used in casting production molding and core making processes, and particularly relates to a phenolic resin binder with less resin content. The phenolic resin binder comprises the following raw materials of thermosetting resol, thermosetting resitol, aqueous alkali with the mass concentration of 50%, a modifier, potassium pyrophosphate, boricacid, an alkaline regulator, ammonium sulfate, lauryl glucoside, polycarbonate diol, an organometallic carboxylic acid compound, sodium lignosulfonate and a silane coupling agent. Compared with the prior art, the phenolic resin binder has the following advantages that different properties of the thermosetting resol and the thermosetting resitol are utilized to perform a reaction with the modifierand the aqueous alkali under a high temperature condition, so that the obtained phenolic resin binder has good binding strength; and compared with the prior art, the addition amount of phenolic resinis reduced, the good pressure resistance strength is ensured, and the phenolic resin binder can be used for casting and enhancing the service performance of molding sand.

The invention relates to an effective method for simultaneously improving the recovery rate of whey protein or protein in MPC, improving the membrane flux and reducing the lactose retention rate through complex enzyme polymerization coupling ultrafiltration. Concretely, laccase and transglutaminase are sequentially added; complex enzyme polymerization and ultrafiltration are effectively combined; a two-section type pretreatment mode is creatively used before complex enzyme polymerization; the mode that the enzyme is not deactivated after the laccase action is also combined, so that the purity and the recovery rate of the whey protein or the protein in the MPC is greatly improved; the membrane flux is improved; the lactose retention rate is reduced. Compared with the prior art, the method has the advantages that the recovery rate of the whey protein or the protein in the MPC is improved by 20 percent; the membrane flux is improved by 30 percent to 40 percent; the lactose retention rate is reduced by 10 percent; the method capable of simultaneously solving a plurality of problems is obtained. The invention also provides a high-quality product of the whey protein or the protein in the MPC; the condition that the product sensitization is obviously reduced is accidentally found; the effect is realized through the result of the complementary and synergic action of all work procedures and parameters; the operability of the method is high; only once filtering is performed; the industrialization is facilitated.

The invention relates to a denture stabilizing sealant and a preparation method thereof. The sealant includes polyvinyl methyl ether / maleic anhydride calcium-sodium mixed salt with number average molecular weight of 200000-400000, cellulose derivatives containing hydroxyl groups, NCO-terminated polyethylene glycol and prepolymer of isophorone diisocyanate. Through the addition of the NCO-terminated polyethylene glycol and prepolymer of isophorone diisocyanate, cross linking effects can be achieved, so that good bonding strength can be well maintained.

The invention relates to an organic surface modification method of inorganic composite powder, in particular, a surface modification method of a conductive material and application thereof in polyacrylate paint. According to the surface modification method of the conductive material and application thereof in polyacrylate paint, inorganic conductive powder is modified by adopting chlorosilane andthen modified by adopting a gas phase method, namely ammonia gas is introduced to aminate the inorganic conductive powder; the aminated inorganic conductive powder is further modified by adopting organic acid-amino trimethylene phosphonic acid; and the amino trimethylene phosphonic acid can react with amino groups on the surface of the inorganic conductive powder, so that the organic phosphonic acid modified inorganic conductive powder material. The modified inorganic conductive material is added into the polyacrylate paint, acidic groups on the surface of the modified conductive powder can becombined with polyacrylate film-forming resin molecular chains through chemical bonds, the crosslinking degree among the polyacrylate molecular chains is improved, and the dispersion stability of thepaint and the conductivity and mechanical properties of a coating of the paint are improved on the whole.

The invention provides a preparation method of an electrolyte separator for the vanadium battery. The preparation method comprises the following steps of 1) preparing quaternary ammonium silane; 2) preparing a polymer; and 3) preparing the separator. The invention also discloses the electrolyte separator, obtained by the preparation method of the electrolyte separator for the vanadium battery, forthe vanadium battery and the vanadium battery employing the electrolyte separator for the vanadium battery as an electrolyte separator. Compared with a traditional quaternary ammonium salt negative ion exchange membrane in the prior art, the electrolyte separator for the vanadium battery, prepared by the method has the advantages of lower cost, better mechanical property, better chemical stability and better thermal stability, more excellent vanadium blocking performance, higher ion conductivity and small deformation, and the application requirement of the electrolyte separator for the vanadium battery is met.