The invention discloses a method for extracting 
lithium from 
magnesium-removal bittern and preparing battery-grade 
lithium carbonate. The method uses a reaction-separating 
coupling technology for separating, extracting a 
lithium resource from 
magnesium-removal bittern and generating the battery-grade 
lithium carbonate, a technology comprises the following steps: 
aluminium salt is added in 
high sodium bittern after 
magnesium removal, and steps of 
nucleation and 
crystallization are carried out with alkali lye in a 
colloid grinder to obtain a lithium-
aluminium composite 
metal hydroxide solid, lithium ions are introduced into a 
solid phase, the sodions stay in a solution, so that lithium ions and sodions are effectively separated. The lithium-
aluminium composite 
metal hydroxide is dissolved by acid to obtain a solution containing lithium ions and aluminum ions, then lithium and aluminium are separated by an 
electrodialysis apparatus, the separated solution containing aluminium can be recycled, a lithium-rich solution is subjected to a 
precipitation reaction, and the battery-grade 
lithium carbonate is obtained. A reaction-separation 
coupling technology is used, while lithium and 
sodium are separated, the battery-grade 
lithium carbonate is prepared, so that high efficiency and high value utilization of the 
salt lake lithium resource can be realized.