The invention discloses a preparation method of a
polyimide fiber solid electrolyte membrane. The
polyimide fiber solid electrolyte membrane is formed by compounding a
metal organic framework material,
polyimide fibers and
polyethylene oxide fibers, the preparation method comprises the following steps: firstly, preparing a composite
fiber membrane with a core-shell structure by a coaxial electrostatic
spinning process, wherein the core is
polyethylene oxide /
metal organic framework composite fiber; the shell is a polyimide /
metal organic framework composite fiber, the vacuum
freeze drying treatment temperature is-40 to-60 DEG C, and the
treatment time is 24-48 hours. And after rolling by a roller press, soaking in a
lithium hexafluorophosphate-containing
ethylene carbonate and ethyl
methyl carbonate solution, and
drying to obtain the polyimide fiber
solid electrolyte membrane. The polyimide fiber solid electrolyte membrane developed by the invention is improved in
mechanical property, Young modulus,
ionic conductivity,
lithium ion transference number and use
voltage, and is expected to be applied to all-solid-state
lithium ion batteries.