The invention discloses a production method of phosphorus pentoxide by directly using phosphorus ore. Phosphorus ore and silica are mixed pro rata, delivered to a heating furnace to be heated and molten, after the molten mass flows into a reaction furnace, carbon is directly added into the high temperature molten mass, the carbon is kept to be excess, the temperature of the molten mass is controlled above 1200 DEG C, thereby leading the molten mass to generate reducing reaction, high temperature and high speed oxygen is sprayed downward into the molten mass through an upper spray gun, thereby providing oxygen for the oxidation of phosphorus vapor and carbon monoxide generated in the reducing zone, and a dished high temperature zone can be formed on the surface of the center of the molten mass, therefore, the heat transfer rate of the mass transfer in the reduction oxidation zone is greatly intensified, the finished quality is ensured, the percent reduction of the phosphorus ore is improved, and the continuous phosphorus pentoxide and phosphonic acid production can be realized. The invention has the advantages that the flow is simplified, the cost is reduced, the finished quality is improved, the percent reduction of the phosphor reaches 98 percent, the energy and resource are saved, the three wastes are basically eliminated, therefore, the invention provides the epoch-making revolution for the phosphor chemical engineering industry.