The invention discloses a BOPP (biaxially-oriented polypropylene) insulating release film. The BOPP insulating release film comprises BOPP, boron nitride, epoxy resin 6101, phenol-formaldehyde resin 2124, melamine, furfural furfuryl alcohol resin, polyacrylamide, polyamide 66, nano-alumina, mica, talc, poly(vinyl butyral), FEP (fluorinated ethylene propylene), PBT (polybutylece terephthalate), PET (polyethylene terephthalate), methoxypolyethylene glycols, PTFE (polytetrafluoroethylene), polymethylmethacrylate, polyphenylene sulfide, organic montmorillonite, paraffin, polyetheretherketone fiber, nano-silica, an antioxidant 1010, a light stabilizer 622, nano-TiO2, PP-g-MAH (maleic anhydride grafted polypropylene), an antifoaming agent, a thickener and a coupling agent. The BOPP insulating release film has excellent insulation, water resistance, corrosion resistance, temperature resistance, weather resistance, adhesiveness as well as heat dissipation and energy storage functions.