The invention discloses an LCP acoustic film, which is prepared from the following raw materials by weight: 15-20 parts of a vinyl fluorine-containing cyclohexyl methyl ether liquid crystal compound/methyl methacrylate/4-acryloyloxybenzophenone/single-terminal vinyl silicone oil copolymer, 50-60 parts of a liquid crystal polymer, 30-40 parts of poly1,4-dihydroxy-2-butene 2,7-naphthalenedicarboxylate, 8-12 parts of vinyl-POSS, 0.2-0.4 part of a heat stabilizer, 0.1-0.4 part of a lubricant, 0.1-0.3 part of an antioxidant and 0.02-0.05 part of an initiator. The invention further provides a preparation method of the LCP acoustic film. According to the invention, the LCP acoustic film retains the advantages of heat resistance, molding processability, dimensional stability, optical performance,electrical performance, chemical resistance, excellent flame retardancy, low dielectric constant and dielectric loss of LCP, and further has good weather resistance, good heat resistance, good mechanical property, good sensitivity and good consistency.