The invention relates to a method for preparing Portland cement clinker. The method comprises the following steps: proportionally mixing tetraethoxysilane, a calcium nitrate hydrate, an aluminium nitrate hydrate, a ferric nitrate hydrate, ethanol, nitric acid, hexamethylenetetramine, acetylacetone, deionized water and the like uniformly to obtain four kinds of mixed liquid, fully stirring the four kinds of mixed liquid respectively at the temperature of 50-70 DEG C until proper viscosity to obtain monomineral sols of the Portland cement clinker, then mixing the four monomineral sols in a massratio of (36-55):(24-40):(11-19):(20-31), ageing the mixture to form gel, carrying out heat treatment on the gel at the temperature of 1150-1200 DEG C for 4-6 hours and cooling the gel to the room temperature, thus obtaining the Portland cement clinker. Compared with the prior art, the method has the following advantages: the preparation process is simple; the reaction process is easy to control;and the product has high uniformity and purity and can be fired at the temperature lower than the temperature in the traditional methods.