The invention relates to a method for preparing
rosin amine
polyoxyethylene ether by spraying method. The reaction is divided into two steps: the first step is to inhale disproportionated
rosin amine into a spray reactor, and when heated to 50-60°C, inhale
phosphorous acid and pump while Raise the temperature to 170-180°C under vacuum, control the pressure in the kettle to 0.2-0.3Mpa, close the vacuum valve, turn on the magnetic circulation pump, the material is sucked out from the kettle and then sprayed into the kettle, and the valve of
ethylene oxide is opened, the material and
epoxy Ethane is sprayed out at the same time, such a circular reaction for 0.8-1.5 hours, heat preservation for 30-40 minutes, and cooling to 90-100 °C; the second step is to vacuumize the inside of the above-mentioned kettle, while inhaling
potassium hydroxide, while raising the temperature to 120- 130°C, keep warm for more than 20 minutes, replace the air in the kettle with
nitrogen, raise the temperature to 165-175°C, close the vacuum valve, turn on the magnetic circulation pump, and spray the material and the remaining
ethylene oxide into the spray reactor at the same time, so that the cycle reaction is 1 -2 hours, keep warm for more than 40 minutes. The method of the invention has short reaction time, complete reaction and good compatibility with other surfactants.