The invention discloses a vehicle brake pad with a composite material. The vehicle brake pad comprises a steel sheet and a friction block; and the friction block includes raw materials of: boron modified phenolic resins, organic silicon modified phenolic resins, barium phenolic resins, phenylacetylene phenolic resins, terminal epoxy liquid reaction nitrile rubber, butadiene rubber, molybdenum disulfide, sisal fibers, carbon fibers, aluminum fibers, molybdenum fibers, polyphenylene benzodioxazole fibers, zinc oxide whiskers, montmorillonoid, vermiculite, nanometer aluminum oxide, cerium oxide, zirconium boride, aluminum silicate hollow spheres, oxidized graphene, copper powder, carbon nanotubes, nanometer carbon black, powder butadiene styrene rubber, ammonium molybdate, and octaphenyl silsesquioxane. The vehicle brake pad with the composite material is excellent in high-temperature resistance and heat resisting stability, high in wear resistance and long in service life.