111results about How to "Unique pore structure" patented technology

The invention provides a method for preparing a porous silicon/carbon composite material by using diatomite as the raw material, which is characterized by comprising the following steps of: with the diatomite as the raw material, performing simple refinement and purification processing to obtain silicon with a porous structure by means of metallothermic reduction; performing mechanical ball-milling with the carbon materials and/or precursors of carbon, hydro-thermal carbonization, pyrolytic carbonization or chemical vapor deposition to prepare the porous silicon/carbon composite material. Thecomposite material can be directly used as the cathode of the lithium ion battery, or can be mixed with other cathode materials to be used as the cathode materials of the lithium ion battery. Compared with a pure silicon material as the cathode material of the lithium ion battery, the porous silicon/carbon composite material has the advantages that the first reversible capacity and the circulation stability of the material are greatly improved. In the method, the inexpensive and accessible natural minerals are used as the raw materials, thus the cost is low and the preparation method is simple.

The invention provides an aluminum oxide carrier and a preparation method thereof. The aluminum oxide carrier takes a mixture prepared by mixing pseudo-boehmite powder prepared by the carbonization method and pseudo-boehmite powder prepared by the aluminum sulfate method according to a weight proportion of 1:0.1 to 5 as a precursor and a complex acid as a peptizing agent; substances such as zirconium, titanium, silicon, alkali metals, alkaline-earth metals, rare-earth metals, carbon black, and the like, are added during kneading process; then the aluminum oxide carrier is obtained after forming, drying and roasting. The physical properties of the carrier are as follows: pore volume is 0.4 to 1.2ml/g; specific surface area is 180 to 370m<2>/g; pores with the diameter being more than 100nm accounts for more than 90 percent of total pore volume; the amount of B acid is 0.1 to 0.3mmol/g; the amount of L acid is 0.2 to 0.5mmol/g. The carrier is especially applicable to the preparation of 1, 4-butanediol catalysts in the two-stage hydrogenation catalytic synthesis of 1, 4-butynediol.

The invention discloses a nano composite material high-wax-content heavy oil viscosity reducer and a preparation method thereof and belongs to the technical field of nano composite material preparation and application. The viscosity reducer is a nano polymethylacrylic acid high carbon alcohol-acrylamide composite material. The preparation method of the viscosity reducer comprises the steps that surface pre-modification is conducted on synthesized MSN by using a silane coupling agent, and polymethylacrylic acid high carbon alcohol-acrylamide composite material powder is obtained through graft copolymerization of methylacrylic acid high carbon alcohol-acrylamide on the surface and pore channels of the MSN. The nano viscosity reducer has a good viscosity reduction effect, is low in cost, simple in production and clean and free of pollution in the process. An experiment proves that the viscosity reduction rate of the nano composite material high-wax-content heavy oil viscosity reducer is 70.30% Daqing Linyuan Sanku high-wax-content heavy oil at the temperature of 40 DEG C and is 79.37% for Daqing Dandong station high-wax-content heavy oil at the temperature of 40 DEG C. The steps are simple, the operation is convenient, and the practicability is strong.

The invention relates to a preparation method and application of a hierarchical-pore HZSM-5 molecular sieve. The preparation method includes following steps: 1), dissolving an aluminum source in water, adding a tetrapropyl ammonium hydroxide solution, adding a silicon source, and mixing to obtain a molecular sieve precursor; 2), pre-crystallizing the molecular sieve precursor; 3), adding sucrose into the molecular sieve precursor after being pre-crystallized, and mixing for hydrothermal crystallizing reaction; 4), after crystallizing reaction is completed, separating, washing, drying and roasting to obtain a hierarchical-pore ZSM-5 molecular sieve; 5), subjecting the hierarchical-pore ZSM-5 molecular sieve and an ammonium salt solution to ion exchange, separating, washing, drying and roasting to obtain the hierarchical-pore HZSM-5 molecular sieve. The hierarchical-pore HZSM-5 molecular sieve prepared by the method can improve aromatization ability and anti-coking ability of the same in the process of biomass catalytic pyrolysis.

The invention relates to the technical field of denitration, in particular to a selective catalytic reduction denitration catalyst, a preparation method and application thereof. The catalyst is prepared from a carrier, transition metal oxide loaded on the carrier, and a rare earth modification additive, as well as a rare earth metal polymer distributed on the carrier as a porous mesh metal frame structure, wherein the total load capacity of the transition metal oxide, the rare earth modification additive and the rare earth polymer on the carrier is 25-35%. The catalyst disclosed by the invention is excellent in catalytic activity at a temperature interval from 200 DEG C to 400 DEG C; the denitration conversion ratio can be up to 90% above; meanwhile, the trace of rare earth modification additive is added to the catalytic system to effectively improve the sintering resistance of the catalyst; the catalyst can effectively improve the lead and sulfur toxic resistance of the catalyst, widens the low temperature reaction window, and prolongs the service life of the catalyst.

The invention discloses a concrete retarder which is prepared from the following components in parts by weight: 4-6 parts of ammonium phosphate, 5-7 parts of ammonium sulfate, 6-8 parts of sodium tripolyphosphate, 10-15 parts of amino trimethylene phosphonic acid, 3-7 parts of gelatin, 1-3 parts of glycerol, 2-4 parts of sodium citrate, 10-15 parts of zeolite powder, 10-15 parts of pumice powder, 3-5 parts of water reducer, 1-3 parts of dispersant and 0.4-0.6 part of surfactant. The concrete retarder has the advantages of good retarding effect, high strength, no pollution and the like, and is a concrete additive with developing future.

The invention discloses a preparing method of a composite adsorbent material of molybdenum disulfide and sepiolite mineral nanometer fiber, and relates to solid adsorbents. The sepiolite mineral nanometer fiber, a molybdenum source and a sulphur source serve as the main raw materials, and through preparation of mixed liquor, suction filtration, washing, drying and roasting, the product of the composite adsorbent material of molybdenum disulfide and sepiolite mineral nanometer fiber is prepared. The defects in the prior art that an existing adsorbent material has poor performance of adsorbing organic dyestuff in dye wastewater, and is high in price, high in reproduction cost, and complicated in preparing technology, and cannot be prepared in batch for industrial production are overcome.

The invention discloses an electrochemical capacitor and electro-adsorption desalination electrode material, which is formed by the combination of nano nickel oxide and nano carbon materials. The preparation method of the electrochemical capacitor and electro-adsorption desalination electrode material comprises the steps of: 1, preparing a nickel salt aqueous solution; 2, mixing the nickel salt aqueous solution with the nano carbon materials; 3, preparing nanocarbon/nickel oxide composite powder; 4, and preparing an electrode. The electrochemical capacitor and electro-adsorption desalination electrode material obtains large capacitance by utilizing oxidation-reduction property of the nano nickel oxide, is high in conductivity, high in specific surface area and high in utilization rate of specific surface area, endows the electrode with high capacitance of capacitor and energy density, has good charging-discharging repeatability, is easy to implement technological parameter control, is even to coat the nano carbon with the nano nickel oxide, and is suitable for industrialized mass production; and the prepared nickel oxide electrode is small in expansion and high in specific capacity, and has good charging-discharging performance, excellent inorganic ion electro-adsorption performance, long service life, and very high practical value.

The invention relates to the technical field of ceramic products and specifically relates to a hydrophobic porous ceramic product and a preparation technology thereof. The hydrophobic porous ceramic product comprises a green body and a glaze material; the green body comprises the following raw materials in parts by weight: 27 parts of silicon nitride, 16 parts of zirconium dioxide, 12 parts of clay, 24 parts of aluminum silicate, 16 parts of cordierite, 19 parts of silicon carbide, 14 parts of kieselguhr, 11 parts of albite, 18 parts of aluminum oxide and 13 parts of fluxing agent; the glaze material comprises the following raw materials in parts by weight: 21 parts of dolomite, 23 parts of silicon carbide, 14 parts of calcium oxide, 17 parts of potassium feldspar, 5 parts of clay and 2 parts of sodium hexametaphosphate. The preparation technology comprises the following steps: modifying raw materials of the green body; injection-molding; de-waxing and biscuit-firing; glazing; sintering. The technology provided by the invention is simple and is suitable for large-scale production. The produced ceramic product has the advantages of high mechanical strength, porous hydrophobic property and high temperature resistance.

The invention discloses a preparation method of a Fe/Fe3C nanoparticle-loaded porous nitrogen-doped carbon-based oxygen reduction catalyst, which comprises the following steps of by using SiO2 as a hard template, carrying out polymerization reaction on hydroxymethylated melamine and ferric acetylacetonate to prepare the novel Fe/Fe3C nanoparticle-loaded porous nitrogen-doped carbon-based oxygen reduction catalyst. The polymer containing iron, nitrogen and carbon is synthesized through polymerization reaction of hydroxymethylated melamine and ferric acetylacetonate, the graphitization degree of carbon can be effectively improved through Fe/Fe3C species formed in the pyrolysis process, the electrical conductivity of the material is enhanced, and then the catalytic activity of the catalytic material is improved. The specific surface area of the Fe/Fe3C nanoparticle-loaded porous nitrogen-doped carbon-based oxygen reduction catalyst prepared by the method is 1084 m<2>g<-1>, the average pore diameter is 7 nm, and the Fe/Fe3C nanoparticle-loaded porous nitrogen-doped carbon-based oxygen reduction catalyst has excellent oxygen reduction performance.

The invention belongs to the field of photocatalytic materials, and particularly relates to a double-doped lanthanum fluoride/attapulgite upconverting composite photocatalytic material and a preparation method and application thereof. The preparation method comprises the following steps: adding La(NO3)3.6H2O, Tm(NO3)3.6H2O, Yb(NO3)3.5H2O, NH4F and hydrochloric acid-modified ATP into deionized water respectively for dissolving, magnetically stirring for 30min for fully mixing, and adjusting the pH value of a system to 4-5; then, transferring to a microwave hydrothermal kettle for a reaction, reacting for 1-2h at the set power of 400W and the set temperature of 160-200 DEG C, centrifuging a prepared sample, washing by using deionized water, then drying the sample, and grinding to obtain a ytterbium-doped and thulium-doped lanthanum fluoride/attapulgite upconverting composite photocatalytic material. The composite photocatalytic material is applied to simulation of photocatalytic gasolinedenitrification, and the denitrification rate can reach 85% after 3h light irradiation.

The invention belongs to the field of chemical new materials and particularly relates to alithium niobate type oxide/attapulgite non-linear optical composite photocatalytic material as well as a preparation method and application thereof. According to the preparation method, LiNbO3 nano-particles with uniform particle sizes are grown on the surfaced of attapulgite in situ by virtue of a sol-gel method, and rich magnesium elements (Mg<2+>) in ATP are doped into LiNbO3 lattices through high-temperature calcination. The preparation method has the beneficial effects that on one hand, by introducing impurity energy level, the bandwidth is decreased, and the stimulation in a visible optical band can be realized, so that the optical response range is increased, and the utilization rate of sunlight is increased; on the other hand, ATP serving as a catalyst carrier has a good dispersion effect, so that the contact surface of the sunlight is increased; besides, ATP has a relatively large specific surface area and a specific pore structure, is capable of exerting specific adsorptive performance and adsorbing partial nitrogen in a photocatalytic nitrogen fixation process and is cooperated withLiNbO3, so that the photocatalytic nitrogen fixation efficiency is improved.

A fluorofurfurlazole cooling polymer used as the catalyst for preparing pyrocatechol by the hydroxylation reaction between phenol and H2O2 with high selectivity is prepared from fluorofurfurylazole and the chloride of transition metal through self assembling and culturing.