The invention discloses a comprehensive 
recovery method of waste 
sodium-
ion batteries, which comprises the following steps: mixing and 
grinding battery black 
powder and a pre-leaching agent, adding a 
reducing agent and 
ammonia liquor for leaching, carrying out 
solid-liquid separation to obtain a 
leachate and a 
solid, adding acid into the 
solid for dissolving, carrying out solid-liquid separation to obtain carbon residue and filtrate, adding alkali into the filtrate for adjusting pH, and separating to obtain aluminum 
hydroxide, alkali is continuously added into the filtrate to adjust the pH, 
manganese hydroxide is obtained through separation, a first 
oxidizing agent, a chelating agent and alkali are added into the 
leachate, 
ammonia distillation and solid-liquid separation are carried out, and a 
cobalt-containing insoluble substance and a 
nickel-containing chelate solution are obtained. According to the method, the battery black 
powder and the pre-leaching agent are subjected to 
ammonia leaching, Mn and Al in a 
reaction system are precipitated, Na, Ni and Co are still stored in the leaching agent, the separation and 
recovery difficulty of valuable 
metal compounds in the leaching agent can be reduced, the subsequent 
precipitation and separation procedures are greatly reduced, then a chelating agent and 
nickel are utilized for generating a chelate, 
nickel and 
cobalt in the solution coexist in the form of different substances, and the separation efficiency is improved. Therefore, high-efficiency separation of nickel and 
cobalt is realized.