The invention relates to a heavy metal collecting agent and a thallium-removal method used for sintering desulfurization waste water. The method is divided into two stages, wherein the first-stage treatment comprises the steps of adjusting the thallium-containing waste water to be alkaline, and adding coagulant; the second-stage treatment comprises the steps of adding agentia and coagulant to supernatant obtained after solid-liquid separation of the first-stage treatment, and effluent is drained outward directly after being subjected to press filtering. The agentia is prepared from, by weight, 20-30% of urea, 1-3% of linear chain small molecule amine substances, 4-9% of carbon disulfide, 0.4-0.7% of epoxy chloropropane, 0.5-0.8% of surfactant and the balance water. A preparation method comprises the steps of adding water for being mixed with urea, amine substances and epoxy chloropropane, stirring the mixture for a certain time at the room temperature, then dropwise adding carbon disulfide, continuing with the reaction, after a period of time passes, raising the temperature, continuing stirring, after the reaction is completed, lowering the temperature to the room temperature, adding surfactant, stirring the mixture uniformly, and obtaining the product. According to the heavy metal collecting agent and the thallium-removal method used for sintering the desulfurization waste water, the agentia is added to the thallium-containing waste water to be treated, and metal complex is formed after the mixture is stirred sufficiently. By means of the process, thallium and other heavy metal ions in the sintering desulfurization waste water can be effectively removed, environmental pollution is avoided, and waste water treatment cost is effectively lowered.