The invention relates to a silicon-fluorine modified styrene-acrylic emulsion and a preparation process thereof. The silicon-fluorine modified styrene-acrylic emulsion comprises the following raw materials: butyl acrylate, styrene, acrylic acid, nonylphenol polyoxyethylene ether, lauryl sodium sulfate, vinyltriethoxysilane, ammonium persulfate, sodium bicarbonate, tetrahydrofuran, methacrylic acid, acrylamide, N-hydroxymethyl acrylamide, hydroquinone, a fluorine-containing monomer, ammonia water and a proper amount of deionized water. The preparation process comprises a pre-emulsification method, a semi-continuous monomer dropwise adding method and an organosilicon monomer post-adding method. According to the invention, the comprehensive performance of the emulsion is studied by a polymerization process, a polymerization temperature, the addition amounts and addition modes of organic silicon and organic fluorine, and the dosage and proportion of an emulsifier; the styrene-acrylic emulsion has the advantages of both organic silicon and organic fluorine, so that the performance of the emulsion is better improved on the basis of effectively reducing the cost of the emulsion, the emulsion with higher market competitiveness is obtained, and the blank of domestic and overseas markets is filled.