The invention discloses a carbon-coated manganous-manganic oxide composite material and a preparation method and application thereof, the composite material takes manganous-manganic oxide as an innercore, and the surface of the composite material is coated with an amorphous carbon layer. The preparation method comprises the following steps: dissolving potassium permanganate and glucose in a solvent, stirring, carrying out hydrothermal reaction on the obtained mixed solution, centrifuging, washing, filtering, and drying to obtain a carbon-coated manganous-manganic oxide precursor; and calcining, pickling, washing and drying the carbon-coated manganous-manganic oxide precursor to obtain the carbon-coated manganous-manganic oxide composite material. The carbon-coated manganous-manganic oxidecomposite material disclosed by the invention has the advantages of good adsorption performance, high catalytic activity, good stability and the like, can realize efficient degradation of organic pollutants, has good reutilization performance, and has good use value and application prospect. The preparation method disclosed by the invention is simple in overall process flow, low in requirements on equipment and reaction parameters and beneficial to large-scale production.