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37results about How to "Simple technological advancement" patented technology

Preparation method of graphene/ ferric oxide/ polyaniline composite material

The invention relates to a preparation method of a graphene / ferric oxide / polyaniline composite material. The method comprises the following steps: ultrasonically uniformly dispersing graphene oxide; adding a sodium dodecyl sulfate aqueous solution and aniline to mix; ultrasonically forming a stable and uniform mixing solution; stirring in an ice-water bath, and dropwise adding ammonium persulfate which is acidized by hydrochloric acid; continuously stirring in the ice-water bath for 12 hours; performing centrifuging and water washing on the obtained dark-green solution to obtain a gel type substance; ultrasonically dispersing the gel type substance into a hydrochloric acid solution; then dropwise adding a saturated ferric chloride solution, and continuously ultrasonically treating; stirring for 1 hour under room temperature; heating through water for 12 hours at the temperature of 180 DEG C; finally performing centrifuging, water washing and freeze drying to obtain the graphene / ferric oxide / polyaniline composite material. The method is simple in process, high in operability, small in equipment investment, and low in production cost; the graphene / ferric oxide / polyaniline composite material prepared through the method is high in electrochemical stability, high in specific capacity, excellent in circulating performance, and outstanding in rate capability.
Owner:SHANGHAI INST OF TECH

Method for preparing graphene/carbon nanotube/carbon nanofiber membrane ternary composite capacitive demineralization electrode

The invention provides a method for preparing a graphene / carbon nanotube / carbon nanofiber membrane ternary composite capacitive demineralization electrode. The method comprises the steps of adding polyacrylonitrile into a well-dispersed graphene oxide and carbon nanotube N,N-dimethylformamide solution, carrying out stirring at a certain temperature so as to prepare a spinning solution, then, preparing a composite film by using an electrostatic spinning technology, and carrying out high-temperature annealing and carbon dioxide activating, so as to obtain a graphene / carbon nanotube / carbon nanofiber membrane ternary composite film. The film obtained by the method can be directly used as the capacitive demineralization electrode. The method provided by the invention is simple, a binder is not required, the prepared electrode material has a flexible characteristic, the assembly is facilitated, and the requirements on environment-friendliness are met; the prepared ternary composite material has a unique microstructure and good electric conductivity, the demineralization performance can be effectively improved, and thus, the ternary composite material has a potential development prospect.
Owner:SHANGHAI UNIVERSITY OF ELECTRIC POWER

Preparation method of visible light catalyst

The invention provides a preparation method of a visible light catalyst. The preparation method comprises the following steps: weighing tetrabutyl titanate, ethanol, hydrazine hydrate and AgNO3, dispersing the tetrabutyl titanate in the ethanol, adding N2H4.H2O, ultrasonically dispersing in icy water bath for 0.5 to 1.5 h, forming TiO2 precursor sol, transferring the TiO2 precursor sol into a hydrothermal kettle, adding AgNO3 into the hydrothermal kettle at an ultrasonic state, reacting for 6 to 10 h at 160 to 200 DEG C, and obtaining the anatase TiO2 / Ag visible light catalyst. Oxygen vacancyformed inside the TiO2 prepared by virtue of the reduction of N2H4.H2O is synergistic with Ag, so that the absorption spectral range of a sample is enlarged, the propagation rate and separation efficiency of photon-generated carrier can be improved, and the visible light catalytic efficiency can be increased. The oxygen vacancy is separately formed inside TiO2 and nano silver corresponding to thevisible light is carried on the surface of TiO2 by virtue of in-situ reduction reaction, and the preparation method is simple and easy to control.
Owner:SHANGHAI INST OF TECH

Preparation method of conductive carbon material with hierarchical porous structure, and pole plate for lead acid battery

The invention provides a preparation method of a conductive carbon material with a hierarchical porous structure. The method comprises: dissolving phenolic resin into an ethanol solution; dissolving a surface active agent F127 into an HCl-containing ethanol solution; then adding ethyl orthosilicate, silicon dioxide colloidal particles and the phenolic resin ethanol solution; transferring a mixture into a container, volatilizing ethanol, performing thermal polymerization in a reaction furnace of 100 DEG C to obtain a faint-yellow transparent thin film, and grinding the thin film into powder; putting the powder into a tubular muffle furnace, and performing carbonization under the nitrogen atmosphere protection; soaking a hierarchical porous structure carbon / silicon oxide composite material into HF of which the content is 5wt%, removing silicon oxide, only retaining carbon components of the hierarchical porous structure, washing a sample by using deionized water, and then performing drying to obtain the conductive carbon material with the hierarchical porous structure. According to the preparation method of the conductive carbon material with the hierarchical porous structure, the internal resistance of a lead acid battery electrode can be effectively reduced, and the utilization rate of active substances and the charge-discharge rate are improved; meanwhile, the electrode structure can be stabilized, and the recycling life is prolonged.
Owner:SHANGHAI UNIVERSITY OF ELECTRIC POWER

Coaxially split dual-core containing microfluid control nozzle and spinning device and spinning method

The invention provides a coaxially split dual-core containing microfluid control nozzle comprising a chief capillary tube, a first bending capillary tube and a second bending capillary tube; the first bending capillary tube and a second bending capillary tube are arranged inside the chief capillary tube side by side; the bending end of each of the first bending capillary tube and the second bending capillary tube goes through from the side surface of the chief capillary tube; the other end of each of the first bending capillary tube and the second bending capillary tube goes through from an outlet end of the chief capillary tube. The invention also discloses a high voltage electrostatic spinning device applying the nozzle; the spinning device comprises a first syringe pump, a first injection syringe, a second syringe pump, a second injection syringe, a third syringe pump, a third injection syringe, a silica gel flexible pipe, a fiber receiving plate and a high pressure generator. An enforcement method of preparing coaxially split dual-core containing structural nanometer fiber is also provided; under high voltage electrostatic field, high voltage electrostatic spinning technology is carried out to effectively prepare nano fiber having complex structural features containing the coaxially split dual-core.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

High-viscosity polymethylphenyl siloxane fluid and preparation method thereof

The invention provides a high-viscosity benzyl silicone oil, which comprises 30-60 parts of diphenyldimethoxysilane; 40-70 parts of dimethyldiethoxysilane; 0.06- 0.12 parts of hydrochloric acid solution; 30-30.5 parts of water; 0.42-0.56 parts of tetramethylammonium hydroxide silicon alkoxide. The present invention also provides a method for preparing the above-mentioned high-viscosity benzyl silicone oil. The high-viscosity benzyl silicone oil of the present invention has high viscosity and high refractive index, and can be applied to many fields such as the preparation of silicone grease, low-temperature lubricating oil, shock absorption of precision instruments, special radiation protection high heat carrier for nuclear power plants, and sealing under continuous high temperature.
Owner:SHANGHAI INST OF TECH

Preparation method for molybdenum dioxide-active carbon composite material

The invention provides a preparation method for a molybdenum dioxide-active carbon composite material. An electrolytic tank is employed, positive and negative electrodes employ inert electrodes, sodium molybdate is employed as a positive electrode solution, an acid solution, a base solution or a saline solution is employed as a negative electrode solution, electrolysis is carried out in a constant current or constant voltage condition, electrolysis is carried out repeatedly, and a molybdic acid solution is prepared; then active carbon is added in the molybdic acid solution in a positive electrode tank, dipping is carried out for 1h-24h in a magnetic stirring condition, filtering is carried out, drying is carried out in a baking oven, and calcining processing is carried out in an inert atmosphere. In the inert gas calcining processing, the positive electrode solution is dried to obtain substances, the substances are placed in a tubular furnace, high-temperature processing is carried out for 2-4h with a heating speed of 2.5-10 DEG C / min in an inert atmosphere, and a molybdenum dioxide-active carbon composite material can be prepared. The method employs the ion-exchange film electrolysis technology and subsequent heat treatment, there are no any additives, the product is pure, there are no any impurities or impurity ions, and subsequent processing is simple.
Owner:SHANGHAI INST OF TECH

Preparation method for positive electrode material lithium cobalt iron phosphate for lithium ion battery

The invention provides a preparation method for a positive electrode material lithium cobalt iron phosphate for a lithium ion battery. The chemical formula of lithium cobalt iron phosphate is LiFe<x>Co<1-x>PO<4> / C, wherein x is greater than or equal to 0.1 and less than or equal to 0.2; the preparation method comprises the steps of adding phosphoric acid into deionized water to prepare a phosphoric acid solution; adding reduced iron powder under a stirring state, enabling the mixture to be reacted to obtain a clear mixed solution; adding a lithium hydroxide solution to the mixed solution; after the solution is cooled, adding the cooled solution to a nanometer ball mill, and adding cobalt hydroxide; carrying out ball milling on the mixture, and then adding a caramel solution, stirring uniformly the ball-milled product, and spraying and drying the product to obtain a spherical lithium cobalt iron phosphate / carbon composite material precursor powder; and calcining the precursor powder at a temperature of 600-700 DEG C under a nitrogen atmosphere to obtain the positive electrode material for the lithium ion battery. The positive electrode material for the lithium ion battery obtained by the invention has relatively high energy density and high cycle performance, and can be expected to be the new generation of high-energy-density positive electrode material for the lithium ion battery.
Owner:SHANGHAI INSTITUTE OF TECHNOLOGY

Dendrobium leaf-containing composition with postprandial blood sugar reducing function and preparation method thereof

The invention provides a dendrobium leaf-containing composition with a postprandial blood sugar reducing function. The dendrobium leaf-containing composition is prepared from the following raw materials in parts by weight: 1 to 3 parts of freeze-dried powder of a dendrobium leaf hydrolysate, 1 to 3 parts of freeze-dried powder of hericium erinaceus hydrolysate, 1 to 3 parts of freeze-dried powderof plumula nelumbinis, 1 to 3 parts of freeze-dried powder of fructus crataegi and 1 to 3 parts of a sweet and sour taste regulator. The invention also provides a preparation method of the dendrobiumleaf-containing composition. The preparation method comprises the following steps: carrying out hydrolysis and freeze drying on cellulase and pectinase of the dendrobium leaves; carrying out the hydrolysis and the freeze drying on the cellulase of hericium erinaceus; carrying out the freeze drying on the plumula nelumbinis and the fructus crataegi; mixing all the materials in proportions, thus preparing the dendrobium leaf-containing composition. A product prepared by the invention is capable of effectively reducing the postprandial blood sugar, all the materials are medicinal and edible materials, and the product can be taken for a long term, is safe and has a good taste. Meanwhile, a utilization range of the dendrobium leaves is broadened, other parts besides stems are fully developed and utilized, and the utilization rate of a dendrobium plant is increased.
Owner:SHANGHAI INST OF TECH

Pingyin rose essential oil GC chromatographic method

A Pingyin rose essential oil GC chromatographic method comprises the following steps: dissolving Pingyin roses into n-hexane, injecting n-hexane into a gas chromatograph, wherein the gas chromatography detection conditions are as follows: chromatographic column: HP-INNOWax elastic capillary column, injection port temperature: 250 DEG C, detector temperature: 250 DEG C, carrier gas: nitrogen, flow velocity: 0.5 mL / min, and split ratio: 100:1; carrying out temperature programming: maintaining the primary temperature (80 DEG C) for 5 minutes, raising the temperature to 220 DEG C at a speed of 2 DEG C / min, maintaining the temperature for 20 minutes; wherein the injection amount is 0.2 [mu]L, the appearance time of citronellol is 47.917 minutes, the appearance time of nerol is 49.653 minutes, and the appearance time of geraniol is 52.061 minutes; after the instrument becomes stable, calculating the contents of main components of Pingyin rose essential oil. The provided method can accurately measure the main components and contents of Pingyin rose essential oil. Moreover, the service life of the chromatographic column is long.
Owner:SHANGHAI INSTITUTE OF TECHNOLOGY

Aluminum-air battery electrolyte compound additive and aluminum-air battery electrolyte and preparation method of aluminum-air battery electrolyte

InactiveCN105720327AReduce hydrogen evolution self-corrosion rateImprove anode activityFuel and primary cellsHydrogenPhysical chemistry
The invention provides an aluminum-air battery electrolyte compound additive, which is prepared from adipic acid and zinc oxide, wherein the molar ratio of the adipic acid to the zinc oxide is (0.5-5.0) to (0.1-1.0). The invention further provides an aluminum-air battery electrolyte. The aluminum-air battery electrolyte is prepared from sodium hydroxide, the adipic acid, the zinc oxide and water; in the electrolyte, the concentration of the sodium hydroxide is 4M; the concentration of the adipic acid is 0.5-5.0mM; the concentration of the zinc oxide is 0.1-1.0mM; and the remainder is water. The invention further provides a preparation method of the aluminum-air battery compound electrolyte. The method can effectively inhibit hydrogen-evolution self-corrosion of an aluminum alloy anode, can negatively shift an open circuit potential of the aluminum alloy anode; in a constant-current discharge test, the aluminum alloy anode has good discharge performance, meets the discharge requirements of an alkaline aluminum-air battery and has a good development prospect.
Owner:SHANGHAI UNIVERSITY OF ELECTRIC POWER

Method for preparing BiOCuS nanosheets by adopting concentrated alkali hydrothermal method

The invention discloses a method for preparing BiOCuS nanosheets by adopting concentrated alkali hydrothermal method. The preparation method comprises the following steps: firstly, sequentially adding reactant precursor sulfur-containing compound, copper oxide or soluble copper salt, bismuth oxide or soluble bismuth salt, strong base and deionized water into a reaction kettle, stirring at room temperature until the reactants are dissolved, and then sealing the reaction kettle and placing the kettle into a vacuum oven at 180-240 DEG C, allowing the raw materials to react for 1-5 days, and finally centrifuging and drying to obtain the BiOCuS nanosheets. The method disclosed by the invention is simple to operate, the preparation is easy, the element stoichiometric ratio is controlled accurately, and the used precursor material is low in cost without toxicity, and the prepared nanosheets can be used as superconducting materials.
Owner:SHANGHAI INST OF TECH

Aqueous anticorrosive coating and preparation method thereof

The invention discloses an aqueous anticorrosive coating. The aqueous anticorrosive coating comprises, by weight, 10 to 40 parts of a hydrophilic modified aliphatic polyisocyanate curing agent, 100 to 120 parts of long-acting water-based composite fluorine-containing resin, 0.05 to 0.1 parts of a leveling agent, 1 to 10 parts of a wetting agent, 1 to 3 parts of a thickener, 0.2 to 1 part of a defoamer, 2 to 5 parts of a film forming aid, 20 to 30 parts of a corrosion inhibitor, 15 to 30 parts of a pigment and a filler, 0.02 to 1.0 part of a catalyst and 20 to 40 parts of deionized water. The invention also provides a preparation method of the aqueous anticorrosive coating. The aqueous anticorrosive coating film has high acid-base resistance and artificial accelerated aging resistance, and can be used in the conventional solvent-based polyurethane coating traditional application fields such as automotive, wood, industrial maintenance, plastic and wind power blades and solar cells having high-performance requirements.
Owner:SHANGHAI INST OF TECH

Method for determining corresponding retained austenite content during bearing steel material thermal processing

The invention discloses a method for determining corresponding retained austenite content during bearing steel material thermal processing. The method includes: measuring the corresponding specific volume of a to-be-determined bearing steel material under different thermal processing states, performing an X-ray experiment on the bearing steel test sample obtained through electrolytic polishing and sample preparation to obtain the retained austenite content, and using the retained austenite content as the horizontal coordinate and the specific volume of the to-be-determined bearing steel material as the longitudinal coordinate to build a relationship, namely a working curve, between the retained austenite content and the specific volume of the to-be-determined bearing steel material; quantitatively determining the corresponding retained austenite content of the to-be-determined bearing steel material under one thermal processing state according to the obtained working curve and the position of the specific volume of the to-be-determined bearing steel material in the working curve or by comparing the specific volume under different thermal processing states. The method is simple in test sample preparation, universal in measuring instrument, convenient to operate, high in experiment data precision, high in repeatability, reliable in data, and the like.
Owner:SHANGHAI INST OF TECH

Lithium manganese silicate material for lithium ion battery positive electrode material and preparation method of manganese silicate material

The invention relates to a lithium manganese silicate material for a lithium ion battery positive electrode material. The molecular formula of the lithium manganese silicate material is LiMnSiO4, the lithium manganese silicate material belongs to a cubic system, the space group is Fd-3m, a three-dimensional structural passage exists, the cell parameter a is equal to 8.16A-bar<3>, the cell volume V is equal to 543.3 A-bar<3>, and Mn is maintained with +3 valence. A preparation method of lithium manganese silicate is also provided. The preparation method comprises the steps of preparing Li2CO3, MnO and SiO2 according to a proportion, sequentially adding the mixture to deionized water for uniform mixing, pouring the mixture to a nanometer sand mill for grinding to obtain paste with the grain size of a suspension substance being 200-300 nanometers, spraying and drying the paste to obtain lithium manganese silicate precursor powder, pressing the precursor powder to form blocks, placing the blocks in a tubular furnace with an oxygen atmosphere for calcination, and taking out and smashing the block material to appropriate sizes, thereby obtaining the lithium manganese silicate nanometer battery positive electrode material. The lithium manganese silicate material prepared according to the method is excellent in electrochemical performance.
Owner:SHANGHAI INST OF TECH

Preparation method of 2-hydroxyacetophenone

The invention discloses a preparation method of 2-hydroxyacetophenone. The preparation method comprises the steps: weighing phenol and acetyl chloride with the molar ratio of phenol to acetyl chloride of 1 to (1.0-1.5), adding phenol and acetyl chloride to a first organic solvent for reaction, carrying out a reaction at the temperature of 20-30 DEG C, then washing with a weak base, and drying and spin-drying to obtain phenyl acetate; adding Lewis acid and an ionic liquid in phenol acetate, wherein the mass of the ionic liquid is 3-10 times that of phenyl acetate, and the reaction temperature is 120-160 DEG C; hydrolyzing the obtained product with a hydrochloric acid solution, and extracting with a second organic solvent; and concentrating an organic layer, then adding a third organic solvent with the volume 1-2 times that of the organic layer, freezing the organic layer, filtering, repeating the operations for 2-3 times, and distilling the obtained filter cake to obtain the product 2-hydroxyacetophenone. The adopted raw materials are low in price, the experimental conditions are mild, the yield is high, the ortho-para ratio can reach 3.55:1, and the preparation method has a great application value in production.
Owner:SHANGHAI INST OF TECH

Nano-fibers with drug two-grade pulse releasing function and preparation method thereof

InactiveCN106860432AImplements secondary pulse release modeDissolve fastOrganic active ingredientsFilament/thread formingFiberWorking fluid
The invention provides nano-fibers with a drug two-grade pulse releasing function. Each nano-fiber comprises an inner core part and an sheath part, wherein the sheath part covers the inner core part; the inner core part and the sheath part extend along the length direction; the inner core part is composed of a drug and a polymer pharmaceutical excipient; the sheath part is composed of a drug and a pharmaceutical excipient which is easily dissolved into water. The invention further provides a preparation method of the nano-fibers; the preparation method comprises the following steps: blending the polymer pharmaceutical excipient and the drug of the inner core part to form a co-dissolved solution, and taking the blended solution as working fluid of the inner core part; blending the pharmaceutical excipient which is easily dissolved into the water and the drug of the sheath part to prepare a co-dissolved solution and taking the co-dissolved solution as working fluid of the sheath part; controlling speeds of injecting core and sheath solutions into a coaxial spinning head through two sets of injection pumps respectively; starting up a high-voltage generator and preparing the nano-fibers under the action of high voltage and static electricity. According to the nano-fibers provided by the invention, the sheath part and the inner core part of each nano-fiber adopt polymer matrixes with different dissolving performances, and the carried drugs can be regulated and controlled and be released in a two-grade pulse manner under the supporting of the structure.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

A kind of preparation method of composite visible light catalyst

The invention provides a method for preparing a composite visible light catalyst. First, according to the steps of elemental P and AgNO 3 Weigh P and AgNO in a molar ratio of 1:3 3 ; Then follow Zr 4+ with Ag + The molar ratio is (1~10): 1. Weigh ZrCl 4 , and then follow the steps of terephthalic acid and ZrCl 4 Weigh terephthalic acid at a molar ratio of (1~1.2):1; disperse the above raw materials into N,N-dimethylformamide solvent, then add acetic acid, and control the reaction temperature to 160~180°C. The time is 20~24h to synthesize Ag 3 PO 4 / Uio‑66 composite visible light catalyst. The preparation method of the present invention is simple, low in cost and relatively pure Ag. 3 PO 4 The photocatalytic effect is better, and it can almost completely degrade 20 mg / L rhodamine B solution within 21 minutes under visible light irradiation.
Owner:SHANGHAI SUPERHIGH ENVIRONMENTAL PROTECTION TECH CO LTD

One sheath double-core microfluidic control nozzle, spinning device and spinning method

The invention provides a one-sheath twin-core microfluid control sprayer which comprises a main capillary tube, a first bent capillary tube and a second bent capillary tube, wherein the first bent capillary tube is arranged in the main capillary tube; the bent end of the first bent capillary tube penetrates through the side wall of the inlet end of the main capillary tube, and the other end of the first bent capillary tube penetrates through center of the outlet end of the main capillary tube; a straight line section of the second bent capillary tube is arranged in the first bent capillary tube; the bent part of the second bent capillary tube penetrates through the side wall of the inlet end of the main capillary tube. The invention further provides a high-voltage electrostatic spinning device which comprises a first injection pump, a second injection pump, a third injection pump, a silica gel hose, a fiber receiving plate, a high-pressure generator and the one-sheath twin-core microfluid control sprayer. The invention further provides an implementation method for adopting the high-voltage electrostatic spinning device to prepare one-sheath twin-core structured nanofiber; the one-sheath twin-core structured nanofiber can be effectively prepared through a single step.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Lithium manganese silicate material for positive electrode material of lithium ion battery and preparation method thereof

The invention relates to a lithium manganese silicate material for a lithium ion battery positive electrode material. The molecular formula of the lithium manganese silicate material is LiMnSiO4, the lithium manganese silicate material belongs to a cubic system, the space group is Fd-3m, a three-dimensional structural passage exists, the cell parameter a is equal to 8.16A-bar<3>, the cell volume V is equal to 543.3 A-bar<3>, and Mn is maintained with +3 valence. A preparation method of lithium manganese silicate is also provided. The preparation method comprises the steps of preparing Li2CO3, MnO and SiO2 according to a proportion, sequentially adding the mixture to deionized water for uniform mixing, pouring the mixture to a nanometer sand mill for grinding to obtain paste with the grain size of a suspension substance being 200-300 nanometers, spraying and drying the paste to obtain lithium manganese silicate precursor powder, pressing the precursor powder to form blocks, placing the blocks in a tubular furnace with an oxygen atmosphere for calcination, and taking out and smashing the block material to appropriate sizes, thereby obtaining the lithium manganese silicate nanometer battery positive electrode material. The lithium manganese silicate material prepared according to the method is excellent in electrochemical performance.
Owner:SHANGHAI INST OF TECH

Sandwich type immunochromatographic test paper for detection of Escherichia coli o157:h7

The invention relates to a sandwiched immunochromatographic test paper used for detecting Escherichia coli O157:H7. The sandwiched immunochromatographic test paper comprises a supporting layer, the upper side surface of the supporting layer is provided with adsorption layers, the adsorption layers sequentially comprise an adsorption fiber layer, a fluorescence antibody fiber layer, a cellulose film and a water absorbing material layer from a test end, the water absorbing material layer is arranged at a handle end, the cellulose film is provided with a detection line and a quality control line, the detection line is formed by an anti-Escherichia coli O157:H7 monoclonal antibody or polyclonal antibody, the quality control line is formed by a goat anti-mouse or rabbit anti-mouse IgG antibody, or a goat anti-rabbit IgG antibody, the fluorescence antibody fiber layer is adsorbed with a fluorescence antibody, and the fluorescence antibody is formed by an FITC labeled anti-Escherichia coli O157:H7 monoclonal antibody or polyclonal antibody. The invention also discloses a production method of the sandwiched immunochromatographic test paper. The test paper has the advantages of simple detection method, strong specificity, high sensitivity, visual property, high accuracy, and realization of lowest detection of 1CFU / mL of trace quantity pollution.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

A kind of preparation method of graphene/iron oxide/polyaniline composite material

The invention relates to a preparation method of a graphene / ferric oxide / polyaniline composite material. The method comprises the following steps: ultrasonically uniformly dispersing graphene oxide; adding a sodium dodecyl sulfate aqueous solution and aniline to mix; ultrasonically forming a stable and uniform mixing solution; stirring in an ice-water bath, and dropwise adding ammonium persulfate which is acidized by hydrochloric acid; continuously stirring in the ice-water bath for 12 hours; performing centrifuging and water washing on the obtained dark-green solution to obtain a gel type substance; ultrasonically dispersing the gel type substance into a hydrochloric acid solution; then dropwise adding a saturated ferric chloride solution, and continuously ultrasonically treating; stirring for 1 hour under room temperature; heating through water for 12 hours at the temperature of 180 DEG C; finally performing centrifuging, water washing and freeze drying to obtain the graphene / ferric oxide / polyaniline composite material. The method is simple in process, high in operability, small in equipment investment, and low in production cost; the graphene / ferric oxide / polyaniline composite material prepared through the method is high in electrochemical stability, high in specific capacity, excellent in circulating performance, and outstanding in rate capability.
Owner:SHANGHAI INST OF TECH

Escherichia coli O157:H7 direct type immunofluorescence chromatography test paper

InactiveCN105606806AStrong specificityStrong specificity and strong sensitivityBiological material analysisCelluloseEscherichia coli
The invention discloses escherichia coli O157:H7 direct type immunofluorescence chromatography test paper. The test paper comprises a supporting layer which is provided with an adsorption layer. A protective layer is arranged on the adsorption layer. The adsorption layer is composed of an adsorptive fiber layer, a cellulose membrane layer and a water absorption material layer, one end of the adsorptive fiber layer is closely connected with one end of the cellulose membrane layer, the other end of the cellulose membrane layer is closely connected with the water absorption material layer, and a detection line is arranged on the cellulose membrane layer and is composed of monoclonal antibodies or polyclonal antibodies composed of escherichia coli O157:H7. The invention further provides a method for preparing the chromatography test paper. The test paper and a detection method are simple, high in specificity, high in sensitivity, visual, accurate and capable of being used for performing qualitative and semi-quantitative detection, the trace contamination of the lowest 1CFU / mL can be detected, the application range is wide, cost is low, and the test paper and the detection method are easy to apply and popularize.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Preparation method of pure-phase bismuth ferrite

The invention provides a preparation method of pure-phase bismuth ferrite. The method comprises a step of preparing a precursor liquid. Fe(NO3)3.9H2O and Bi(NO3)3.5H2O are dissolved in a solvent to obtain the precursor liquid with the metal ion concentration being 0.2 mol / L. Ammonia water is mixed with a ammonium bicarbonate solution to obtain a precipitating agent. In magnetic stirring, the precursor liquid is uniformly added to a precipitating agent solution dropwise till the pH value of a titration final point is controlled in 9-10. After titration is completed, stirring is continuously carried out to obtain a precipitate. The precipitate is allowed to stand and age, filtration is carried out, and the obtained product is washed with deionized water and absolute ethyl alcohol and is dried to obtain precursor powder. The precursor powder is put in a muffle furnace, the temperature is raised for calcination, and the obtained product is cooled to obtain pure-phase bismuth ferrite powder. The preparation method and the equipment are simple, and the pure-phase bismuth ferrite can be prepared in a large amount at one time. The preparation method is free of organic solvent and is green and eco-friendly, and the pure-phase bismuth ferrite is complete in crystallization and uniform in powder size.
Owner:SHANGHAI INST OF TECH

A kind of phospholipid surfactant multi-structure liposome and preparation method thereof

The invention discloses a phospholipid surfactant multi-structure liposome. The phospholipid surfactant multi-structure liposome comprises, by weight, 0.1-20% of phospholipid, 0.01-10% of co-emulsifiers, 0.1-10% of liquid grease, 0.05-5% of additives and the balance deionized water. The invention further provides a preparation method of the phospholipid surfactant multi-structure liposome. The preparation method includes mixing the phospholipid with the co-emulsifiers, the liquid grease and the organic additives, and heating the mixture to obtain an oil-phase component; mixing the inorganic additives with the deionized water, heating the mixture to obtain an aqueous-phase component, and adding the oil-phase component into the aqueous-phase component for homogenization; stirring and cooling at a high speed until the temperature is lowered to the room temperature, adding preservatives, and continuing to stir to obtain the phospholipid surfactant multi-structure liposome. The phospholipid surfactant multi-structure liposome has the advantages that a multi-structure can be formed by phospholipid surfactant, namely lecithin, applied in the preparation method through self-assembly, simplicity in operation is achieved, high skin moisture retention and penetrability are realized, and cosmetics made from the phospholipid surfactant multi-structure liposome are more safe and reliable.
Owner:上海欧润化妆品有限公司

A kind of effervescent drug producing polylactic acid glycolic acid and its preparation method and application

The invention discloses a bubble-producing polylactide acid-glycolic acid effervescence drug. The bubble-producing polylactide acid-glycolic acid effervescence drug comprises polylactide acid-glycolic acid, an effervescence substance, a chemotherapy drug and an organic solvent, wherein the concentration of polylactide acid-glycolic acid in the organic solvent is 0.1-1.0g / mL; the effervescence substance consists of organic acid and alkaline substance, the concentration of organic acid in the organic solvent is 0.1-0.5g / mL, and the concentration of alkaline substance in the organic solvent is 0.1-0.5g / mL; the concentration of chemotherapy drug in the organic solvent is 1-10g / mL. The invention also provides a preparation method of the bubble-producing polylactide acid-glycolic acid effervescence drug and a bubble-producing polylactide acid-glycolic acid effervescence drug stent material. The bubble-producing polylactide acid-glycolic acid effervescence drug has the advantages that under the irradiation action of HIFU (high intensity focused ultrasound), the effervescence substance produces air bubbles in the stent material, so that the ablation effect of HIFU on tumors is improved; the loaded chemotherapy drug is released out, and the capability of stent chemotherapy treating the tumors is realized.
Owner:UNIV OF SHANGHAI FOR SCI & TECH +1

An electrospun nanofiber with drug radial isolation distribution characteristics and preparation method thereof

The invention provides a drug-loaded nanofiber with a radial discontinuous drug distribution characteristic. The drug-loaded nanofiber comprises an inner core layer, wherein a middle layer is arranged at the periphery of the inner core layer; an outer surface layer is arranged at the periphery of the middle layer; the inner core layer, the middle layer and the outer surface layer coaxially stretch; drugs in the fiber are radially distributed discontinuously; and the inner core layer and the outer surface layer contain the drugs. The invention further provides a preparation method of the drug-loaded nanofiber. The preparation method comprises the steps that a spinnable polymer solution is prepared into a mother solution; the drugs are added to the mother solution to form an inner core layer working fluid and an outer surface layer working fluid; the inner core layer working fluid and the outer surface layer working fluid are respectively packed into an inner core layer fluid injector and an outer surface layer fluid injector; a middle layer fluid injector is filled with the mother solution; the inner core layer fluid injector, the middle layer fluid injector and the outer surface layer fluid injector are respectively connected with three injection pumps; injection rates of the three fluid layers in a three-stage coaxial spinning head are respectively controlled by the three injection pumps; and the nanofiber with the radial discontinuous drug distribution characteristic is prepared by the action of high-voltage static. The nanofiber prepared by the method is clear in structure, small in nano diameter and good in linearity.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Method for carrying out in-situ rapid detection pretreatment on pesticide residues in vegetables and fruits

The invention discloses a method for performing in-situ rapid detection pretreatment on pesticide residues in vegetables and fruits, which comprises the following steps of: preparing a sample: chopping and mashing a vegetable or fruit sample into homogenate, and putting the homogenate into a polyethylene bottle; the extraction method comprises the following steps: weighing a homogeneous sample, adding acetonitrile, shaking, filtering with filter paper, and collecting filtrate; adding an extraction salt bag into the filtrate, vigorously shaking, and standing at room temperature until the solution is layered; and a purification step: sucking the supernatant, carrying out primary purification on the supernatant through a filtration type purification column, and then passing through a microfiltration membrane for determination. Compared with a traditional QuEChERS pretreatment method, a novel rapid filtration method is used as a purification method, and meanwhile, a centrifugation step is omitted by extracting a target object through standing and natural layering after filtration. The method is simple to operate and high in treatment speed, does not need other auxiliary instruments, and is suitable for serving as a pretreatment method for on-site in-situ rapid detection.
Owner:上海市农产品质量安全中心

Ginkgo fruit and ganoderma lucidum concentrated solution and preparation method thereof

The invention provides a ginkgo fruit and ganoderma lucidum concentrated solution. The ginkgo fruit and ganoderma lucidum concentrated solution is prepared from raw materials in parts by weight as follows: 1-3 parts of a ginkgo fruit hydrolysate, 1-3 parts of a ganoderma lucidum hydrolysate and 0.5-2 parts of sugar acid taste regulatory substances. The invention also provides a preparation methodof the ginkgo fruit and ganoderma lucidum concentrated solution. The preparation method comprises the steps as follows: preparing a ganoderma lucidum sporocarp cellulase hydrolysate; pretreating ginkgo fruits; hydrolyzing the treated ginkgo fruits with amylase and pectinase; compounding the ganoderma lucidum hydrolysate and the ginkgo fruit hydrolysate; and performing vacuum concentration to obtain the ginkgo fruit and ganoderma lucidum concentrated solution. The ganoderma lucidum and the ginkgo fruits are matched and complementary in nutrients and functions, the healthcare function is enhanced, and on the other hand, the absorption and utilization rates of polysaccharides in the ginkgo fruits and cellulose substances in the ganoderma lucidum are increased. Meanwhile, triterpene substancesin the ganoderma lucidum and flavonoid substances in the ginkgo fruits have antibacterial and anti-oxidation functions, and the expiration date is prolonged in the absence of a preservative and an antioxidant.
Owner:SHANGHAI INST OF TECH
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