101results about How to "Controllable particle size distribution" patented technology

The invention belongs to the technical field of bioseparation material, in particular to a magnetic composite microsphere with nucleocapsid structure and a preparation method thereof. Nano ferroferric oxide decorated by oleic acid is firstly used as raw material, and is polymerized through template fine emulsion so as to prepare the monodisperse magnetic composite microsphere with high magnet content; and then the monodisperse micosphere is polymerized through seed emulsion and is added with different amount of shell monomer to prepare the magnetic composite microsphere with the nucleocapsid structure and the magnet content of 20wt percent to 80wt percent. The grain size of nucleocapsid composite microsphere is in narrow distribution, and the magnet content of the microsphere is controllable and the surface has functional reactive group; therefore, the microsphere of the invention can be surface-modified into a magnetic carrier of biological active molecule by chemical crosslinking to be applied in the biomedicine field. The method of the invention can be simply operated and the process of which can be controlled, thus having industrialized prospect.

The invention discloses a method for preparing spherical active carbon employing water soluble bitumen. The method comprises the following processes: washing commercial sulfonated asphalt to obtain a complete water-soluble material; preparing a bituminous solution from the obtained water-soluble material or water-soluble mesophase pitch and deionized water; carrying out spray granulation on the bituminous solution, so as to obtain a bituminous ball; carbonizing and activating the bituminous ball, so as to obtain the spherical active carbon. The method has the advantages that the commercial sulfonated asphalt and the water-soluble mesophase pitch are adopted, so that the spherical active carbon is low in price and wide in source, no organic solvent is added in the balling process, the bituminous ball is controllable in particle size distribution, the prepared spherical active carbon is large in specific surface area, and industrial production is easy to achieve.

This invention discloses a method for preparing Ag nanoparticles. The method comprises: (1) mixing acid solution of chitosan and AgNO3 solution to obtain a mixed solution; (2) adjusting the pH value to 3.0-5.0; (3) irradiating without oxygen. The deacetylation degree of chitosan is greater than or equal to 70%, and the average molecular weight is less than or equal to 20000. The concentration of chitosan in the mixed solution is 0.001-0.05 wt. %, and that of AgNO3 is 0.01-23.5 mM. The obtained Ag nanoparticles have such advantages as small average particle size, uniform particle size distribution, high solid content, high water solubility, and high biocompatibility.

The invention provides a method for preparing flamazine/bacterial cellulose composite wound dressing, which comprises the following steps of: performing pretreatment and purification treatment on a bacterial cellulose membrane to obtain purified bacterial cellulose; preparing flamazine suspension with the granularity of 50 to 5,000 nm under dark condition; reacting the bacterial cellulose membrane with the flamazine suspension to form a flamazine/bacterial cellulose composite membrane; and performing drying treatment to obtain a dry flamazine/bacterial cellulose composite membrane, or performing extruding dehydration to obtain a wet flamazine/bacterial cellulose composite membrane with different water content values to prepare the flamazine/bacterial cellulose composite wound dressing. The prepared flamazine/bacterial cellulose composite wound dressing has high mechanical performance, high antibacterial property, and high water and air permeability or good drainage and moisture absorption effects, can promote the drying, scabbing and healing of wound, and is used for preventing and treating the secondary wound infection of second-degree and third-degree burn or scald.

The invention discloses a preparation method of particle size distribution concentrated and controllable high-purity tantalum powder. The method includes hydrogenating high-purity tantalum ingots into tantalum chips, placing the tantalum chips into a grinder for beating and grinding in an open manner prior to sieving, performing high-frequency oscillation classification on sieved tantalum powder, then subjecting the classified tantalum powder to low-temperature vacuum drying, and dehydrogenizing the dried tantalum powder. In the grinding and classification processes, all appliances in contact with the tantalum powder are made of tantalum with the purity more than 99.99%. Preferably, during classification, selection liquid is adopted as a medium. By means of the technology, in the production process of the tantalum powder, since high-purity media are adopted totally, few new impurities are brought in, subsequent pickling or other purification technologies are not required, technological process is shortened, and economy and environmental protection are realized; besides, the tantalum powder is low-carbon and low in oxygen and impurity; the liquid medium directly contacts with the tantalum powder during classification, and accordingly surface adhesion of coarse tantalum powder and fine tantalum powder is prevented; the classified tantalum powder is clean in particle and concentrated and controllable in particle size distribution.

The invention discloses a preparation method of hollow carbon bowl powder, and belongs to the technical field of preparation of inorganic materials. According to the method, a direct biological raw material or waste is adopted as a carbon source, a soft template is used as a template, and the hollow carbon bowl powder material with high dispersity, controllable particle size distribution and size,an inner hollow structure, morphology of a concave bowl-shaped structure, controllable wall thickness of the carbon bowl, and the like is prepared. The preparation method comprises the following steps: taking the carbon source, deionized water and the soft template agent as raw materials, respectively dissolving the carbon source and two surfactants in the deionized water to form three solutions,then mixing the three solutions according to a certain ratio, uniformly carrying out stirring to obtain a mixed solution, putting the mixed solution into a hydrothermal reaction kettle, and carryingout heating for a reaction to obtain a product. The method has the advantage that the direct biological raw material or biological waste is used as the carbon source, and aims to provide the novel utilization mode of biological wastes, so that emission of wastes is reduced, the wastes are converted into the functional carbon material, the process is simple, and the preparing and removing processesof a template in a hard template method is omitted.

A Cu-alloy covering powder for covering a Cu-alloy layer on the surface of the Fe particle to become a composite particle less than 80 meshes is disclosed. The brass alloy powder contains proportionally Cu, Zn and Fe. The bronze alloy powder contains proportionally Cu, Zn, Sn, Fe, etc.

The invention relates to a method for preparing noble metal nano material with adjustable particle size by bacteria, and belongs to the technical field of preparation of inorganic nano material. The method comprises the following steps of placing the bacteria in a culture liquid, uniformly mixing, and adding inorganic salts into the culture liquid to ferment, so as to obtain inorganic noble metal nano particles; or placing the bacteria in the culture liquid, culturing, fermenting, and adding the inorganic salts into the bacteria fermenting liquid to carry out reaction, so as to obtain the inorganic noble metal nano particles. The size of the nano particle is controlled by changing the adding amount of the inorganic salts. The bacteria are yeast and lactic acid. The inorganic salts are the inorganic salts of Cu (copper), Ag (silver), Pt (platinum) and Pd (palladium). The method has the advantages that the bacteria, the culture liquid and the inorganic salts are used as raw materials, the noble metal nano material is prepared by the bacteria fermenting, the size of the nano particle is controlled by changing the adding amount of the inorganic salts, and the composite noble metal nano particles different in the configuration are prepared by adding inorganic salts different in the type; and the preparation method is simple, quick and safe.

The invention discloses a preparation method of carbon reinforced metal/metal oxide composite powder and belongs to the field of composite material preparation. The preparation method comprises the steps that a cavity is heated to reach metal salt decomposition temperature, then a metal salt solution and carbon dispersion liquid are mixed, the mixture is atomized into small liquid drops (generally nanoscale) by using a spraying device, the small liquid drops are led into the cavity, pyrolytic reaction instantly occurs under the high-temperature effect of the cavity to generate metal oxide and carbon composite powder, or the small liquid drops are led into the reduction atmosphere, while pyrolysis and reduction reactions occur to generate the metal oxide and carbon composite powder, and then the powder is collected through a dust collection device. The preparation method does not destroy original morphology of carbon, the prepared composite powder particles are smaller in size (can reach the nanoscale), size distribution is more controllable, the dispersity of the carbon in a matrix is more excellent, and the preparation method further has the advantages that the method is simple and convenient to operate, and large-scale batch production is easy to achieve.

The invention discloses a preparation method for bimodal active alumina micropowder. The method comprises the following steps: (1) calcining industrial alumina powder at different temperatures so as to obtain calcined alumina powders with a variety of original crystalline sizes; (2) selecting two calcined alumina powders with different original crystalline sizes and carrying out ball milling so as to obtain the bimodal active alumina micropowder, wherein the mass ratio of the two calcined alumina powders with different original crystalline sizes is 0.2-5: 1. The preparation method for the bimodal active alumina micropowder provided by the invention is simple and can obtain bimodal-distribution active alumina micropowder; and the obtained bimodal alumina micropowder can be used for refractory products and can improve performances like construction performance, compactness, slag resistance and mechanical strength of the refractory products.

The invention discloses a new process for preparing high purity aluminum oxide powder. The processed is carried out based on the fundamental principle of ultrasound electrochemistry, wherein electrode reactions in primary cells between metallic aluminium and air is formed under ultrasound action in a pure water system, and in-situ activation is carried out on the surface of the high purity metallic aluminium by the cavitation of an ultrasonic field, which can promote the activation of the surface of the metallic aluminium and the primary cell reaction between the metallic aluminium and the air as well as the hydrolysis reaction of the metallic aluminium. The method has simple principle, concise process, short technological procedures, low specific volume and energy consumption, environmental protection and no pollution. As under the entire ultrasound-electric field coupling condition, the reaction is moderate and controllable, and the obtained high purity Al (OH) 3 gel has small primary particle size, uniform particle size distribution, high activity, good flowability, particle appearance approximate to sphere and easy purity control. The obtained Al (OH) 3 gel is processed then by thermal treatment, and the high purity aluminum oxide powder with different forms can be obtained at different thermal treatment temperatures. The product has high purity, excellent particle characteristics and incomparable advantages over the products prepared by other production methods in the aspects of purity and particle shape.

The invention discloses a method for preparing spheroid manganous-manganic oxide from a manganese sulfate solution. The method includes the following steps that an electrolytic manganese metal sheet is dissolved, impurity-removed and purified to obtain the manganese sulfate solution with low impurity content; the manganese sulfate solution, ammonia water and additives are added into a reaction kettle in a parallel flow mode, a sufficient amount of an oxidizer is added for one-step oxidation under the stirring condition, and the reaction temperature is 50-90 DEG C; and after addition of the manganese sulfate solution is completed, the ammonia water is continued to be added for 6-10 h to control the pH value of a reaction system to be 4.5-9.5, adding of the ammonia water is stopped and thenstirring is continued, heat preservation and aging are conducted for 4-20 h, then a product is filtered and washed, and the spheroid manganous-manganic oxide is obtained by drying at 120 DEG C. The prepared spheroid erical manganous-manganic oxide D50 is 4-20 [mu]m, the tap density is greater than or equal to 2.0 g/cm<3>, and the Mn content is greater than or equal to 70.5%. The method is simple in process flow and low in production cost, and industrial production is easy to realize.

The invention discloses a preparation method of amorphous SiOC ceramic powder, which comprises the following steps: 1) carrying out low-temperature crosslinking curing on a precursor polymer, crushing the crosslinking curing product, and screening to obtain precursor particles, wherein the precursor polymer is linear polycarbosilane or a mixture of linear polycarbosilane and linear polysiloxane; 2) carrying out pyrolysis reaction on the precursor particles to obtain pyrolysis ceramic particles with irregular particle morphology, of which the particle size is 60 mu m-2mm; and 3) carrying out ball milling on the pyrolysis ceramic particles to obtain the amorphous SiOC ceramic powder. The amorphous SiOC ceramic powder has the characteristics of controllable Si, O and C element contents, controllable powder particle size and controllable crystallization temperature. The method has the advantages of simple preparation technique, low cost and the like, and is suitable for industrial production.

The invention relates to drug-loaded egg protein microspheres and a preparation method thereof, belonging to the field of drug controlled release. The invention aims at solving the technical problem of providing the drug-loaded egg protein microspheres and the preparation method thereof. A vector of the drug-loaded egg protein microspheres is egg protein. The preparation method comprises the following steps: mixing a surfactant with an oily component to obtain an oil phase; adding a mixed liquor of the egg protein and drugs to the oil phase to stir and emulsify, and then directly heating and solidifying or adding an aldehyde curing agent to carry out crosslinking solidification; demulsifying by using a petroleum ether after solidification is ended; and cleaning and centrifuging by using isopropyl alcohol, and carrying out freeze-drying, so as to obtain the drug-loaded egg protein microspheres. The microspheres disclosed by the invention have good biocompatibility and biological activity; the particle sizes are 0.2-20mu m, and can be adjusted according to different solidification methods; and the microspheres are good in controlled release effect, are applied to a plurality of drug-delivery ways, such as injection, oral administration and the like, and are wide in material source, low in price, simple and feasible in preparation process and low in production cost.

The invention discloses a method for preparing high alpha-phase silicon nitride by utilizing porous silicon. The method comprises the following steps: with the porous silicon as a raw material, in the nitrogen atmosphere, sequentially carrying out treatments including high-temperature calcination and grinding to obtain the high alpha-phase silicon nitride. With the adoption of the method of preparing the high alpha-phase silicon nitride by utilizing the porous silicon, the silicon nitride with high alpha phase content and uniform particle size distribution is efficiently prepared. The method is simple in process, controllable in performance, short in production period and low in cost, is capable of greatly lowering the production energy consumption and is suitable for large scale industrial production.

The continuous preparation process of high purity nanometer alumina includes the following steps: high temperature gasifying aluminum trichloride, continuous mixing with H2 and O2 in a re-mixer, high temperature hydrolysis and condensation reaction of aluminum trichloride in the high temperature generated through burning H2 inside a reactor, and aggregating the reaction product, gas-solid separation, dechlorinating, floating, etc. to obtain high purity nanometer alumina. By means of controlling the material ratio, the cooling rate in the reactor, and the length and temperature of the aggregator, nanometer alumina powder of different grain sizes may be obtained. By means of tail gas treatment, circular utilization of aluminum trichloride and absorption of HCl to prepare hydrochloric acid, the present invention realizes the best utilization of resource.

The invention discloses a positive electrode material precursor, a preparation method and applications thereof. The preparation method comprises:carrying out a three-stage co-precipitation reaction ona salt solution, an alkali solution and an ammonia solution to obtain a product, wherein each stage of the co-precipitation reaction comprises a seed crystal generation process under a high pH condition and a crystal grain constant-speed growth process under a low pH condition; and aging, washing and drying the product to obtain a positive electrode material precursor. According to the invention,the precursor material formed by mixing large and small secondary spherical particles, wherein the octahedral gaps and the tetrahedral gaps between the large particles are filled with the small particles so as to meet the close packing requirements of the material; compared with the conventional ternary precursor material, the material of the invention has the increased tap density of 2.2-2.5 g/cc, and easily meets the requirements of lithium ion batteries on high energy density at present; and the method is simple in process, controllable in productivity and easy for large-scale production and application.

The invention provides a fire disaster simulating experiment platform for an underground traffic switching channel. The platform comprises a model main body simulating the underground traffic switching channel, a combustor butted to the model main body and generating smoke, and a smoke imaging system, wherein the smoke imaging system comprises laser sheet light sources and image recording devicesrecording smoke distribution images; the plurality of laser sheet light sources are distributed in the model main body, and planar laser emitted by the laser sheet light sources is parallel to the flowing direction of smoke; the plurality of image recording devices are in one-to-one correspondence with the laser sheet light sources and are distributed outside an observation window of the model main body; and each laser sheet light source and each image recording device in pair which correspond to each other are provided with light filters filtering out laser with the same wavelength. The firedisaster simulating experiment platform for the underground traffic switching channel can conveniently research the horizontal spreading feature of the smoke, and is particularly suitable for simulating the fire disaster of the underground traffic switching channel.

The invention discloses a nitrogen-doped mesoporous hollow carbon sphere loaded metal-based nano catalyst and a preparation method thereof. The catalyst is prepared through different methods, the expression of the catalyst is M (at) NHCS, NHCS is nitrogen-doped mesoporous hollow carbon spheres, and M is any one of metal nickel, copper, cobalt, iron, ruthenium, platinum, palladium, iridium, rhodium and gold. The hollow carbon spheres are used as a stable carrier, and metal can be loaded to realize a functionalization effect. Metal is loaded on the surfaces of the carbon spheres, so that metal particles are not easy to agglomerate, and more active sites can be provided. Besides, the hollow carbon sphere also has an adjustable pore structure and an easily modified surface, and the macroscopic size and the shell thickness can be adjusted by a synthesis method, so that the hollow carbon sphere material has huge performance potential.

The invention discloses a method for preparing B4C nano-powder through in-situ combustion synthesis, and belongs to the technical field of powdering in a powder metallurgy process. The method comprises the steps of mixing boron oxide and magnesium powder at a molar ratio, feeding into a high-energy ball mill for mechanical activation treatment; mixing with carbon nano-powder evenly at a molar ratio, putting into a mold, pressing into a block blank at 10-60MPa and then putting into a self-propagating reactor for triggering self-propagating reaction; immersing the product into diluted hydrochloric acid and carrying out intensified leaching in a closed reaction kettle; and finally carrying out spray pyrolysis to obtain a high-purity boron carbide nano-powder product. The high-purity and high-activity nano B4C powder is prepared through the method. The method is low in raw material cost, low in energy consumption, simple in operation, and low in requirement for technological conditions and instruments and equipment; and a foundation is laid for industrial production. By adopting high-energy ball milling activation, the disadvantages of a traditional magnesium heat reduction method are improved; and by adopting a self-propagating powder technology, the product has the advantages of high purity, controllable particle size distribution and high powder activity.