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81results about How to "Raw materials are economically available" patented technology

Method for treating chlorinated organic pollutants in underground water by using slow-release compound repair material

The invention discloses a method for treating chlorinated organic pollutants in underground water by using a slow-release compound repair material. The method comprises the following steps: (1), preparing charcoal through high temperature pyrolysis; (2), pre-treating zero-valent iron through acid pickling; (3), adding water into the charcoal, then adding xanthan gum and an organic carbon source, and finally, adding zero-valent iron, and through steps of treating, obtaining the slow-release compound repair material; then treating chlorinated organic pollutants in underground water by adopting an in situ injection repairing method or an in situ PRB repairing method. According to the method provided by the invention, the xanthan gum with high mechanical strength and strong mass transfer performance is used as a novel slow release embedding medium, the physical adsorbent charcoal, the chemical reductant zero-valent iron and the bioreductive drug organic carbon source are taken as effective components for composite embedding, so that gel microspheres with stable structures are formed, and the method provided by the invention has the advantages of sustained release, simple and convenient operation, low cost, environment friendliness and the like, can effectively achieve physically, chemically and biologically collaborated and enhanced remediation, and can effectively remove target pollutants.
Owner:SHANGHAI ACADEMY OF ENVIRONMENTAL SCIENCES

Method for removing trace arsenic from aqueous solution

The invention discloses a method for removing trace arsenic from an aqueous solution. The method comprises the steps of: adjusting the pH value of an arsenic-containing aqueous solution with an acid or a base by utilizing the adsorption and coprecipitation principle through culturing and analyzing the plants growing in arsenic environment, adding a copper-containing reagent, an iron-containing reagent or a zinc-containing reagent or simultaneously or respectively adding a mixture of two or more of the copper-containing reagent, the iron-containing reagent and the zinc-containing reagent in the presence of calcium salts, magnesium salts and carbonate, and precipitating, wherein the arsenic content in the water, from which arsenic containing slag is separated, is detected to be less than 0.01mg / L. The method has the characteristics that the trace arsenic element in the aqueous solution can be removed by controlling the addition amounts of the copper-containing reagent, the iron-containing reagent and the zinc-containing reagent as well as the pH value of the solution; the use raw materials are economical and easily available, and harmful elements are not introduced to the system, thus the method is an environment-friendly and economical treatment process; and the process can be widely applied to treatment of arsenic-containing wastewater discharged in the fields of metallurgy, chemical industry, pesticide, pigment, fuel, papermaking, leather manufacture and the like.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY

Slow-release compound repair material for treating chlorine-containing organic pollutants in groundwater and preparation method thereof

ActiveCN104944568AAchieving Synergistic Enhanced RestorationEfficient removalOther chemical processesWater contaminantsSorbentMicrosphere
The invention discloses a slow-release compound repair material for treating chlorine-containing organic pollutants in groundwater and a preparation method thereof. The preparation method comprises the steps of (1) preparing biochar by high-temperature pyrolysis; (2) pretreating zero-valent iron by acid pickling; and (3) adding water into the biochar, adding xanthan gum and an organic carbon source, adding zero-valent iron finally, and carrying out multi-step treatment on the obtained mixture so as to obtain a slow-release compound repair material for treating chlorine-containing organic pollutants in groundwater. According to the invention, by using the xanthan gum with high mechanical strength and strong mass transfer performance as a novel slow-release embedding agent, the biochar (as a physical adsorbent), the zero-valent iron (as a chemical reductant) and the organic carbon source (as a biological reductant) which are taken as effective components are compositely embedded so as to form constitutionally stable gel microspheres, and the slow-release compound repair material has the advantages of long-term slow-release, easy operation, low cost, environment friendliness, and the like, and can effectively realize the physical, chemical and biological synergistic reinforced repair, therefore, the material can remove target pollutants more efficiently.
Owner:SHANGHAI ACADEMY OF ENVIRONMENTAL SCIENCES

Highly-transparent flame-retardant modified organic glass and preparation method thereof

The invention provides highly-transparent flame-retardant modified organic glass and a preparation method thereof. The highly-transparent flame-retardant modified organic glass comprises a polymer shown in a formula (I). According to the highly-transparent flame-retardant modified organic glass, a flame retardant is directly introduced into an organic glass molecular chain through a copolymerization reaction, the obtained flame-retardant organic glass has excellent flame resistance, transparency and colorability, and secondary pollution does not exist in the using process. The preparation method comprises the steps that methyl methacrylate is adopted as solvent; on the condition that a polymerization inhibitor exists, 2-oxo-2-chlorine-5,5-dimethyl-1,3,2-phospho heterocycle hexane and N-hydroxymethyl acrylamide are reacted to obtain mixed liquor of a phosphorus and nitrogen reaction type flame retardant shown in a formula (II) and vinyl acetate, under the action of an initiator, prepolymerization, low temperature polymerization in a mold and demoulding are conducted, and the highly-transparent flame-retardant modified organic glass is obtained. A methyl methacrylate monomer is adopted to serve as the solvent, solvent recovery does not exist in the preparation process, industrial three wastes are not produced, separation and purification are not needed for a product, operation is easy and convenient, and industrial production is easy.
Owner:黄国波

Slow-release repairing material for organochlorine pesticide contaminated farmland soil

The invention discloses a slow-release repairing material for organochlorine pesticide contaminated farmland soil. A preparation method of the slow-release repairing material comprises the following steps: preparing a biochar carrier; pretreating zero-valence iron powder; and preparing the slow-release repairing material. The slow-release repairing material comprises, by mass, 15-30% of the biochar, 10-20% of an organic carbon source, 5-10% of zero-valence iron, 5-10% of illite and 25-50% of guar gum. The organic carbon source can promote the activity of degrading bacteria as a growth matrix,and the biochar has a strong physical adsorption effect on organochlorine pesticides and provides inorganic nutrient minerals for soil; above effective components are organically combined by an embedding agent to realize the physical-chemical-biological synergistic enhanced repairing of the organochlorine pesticide contaminated farmland soil, so the pollutant removing effect is good, the treatmentlong-acting property of the organochlorine pesticides by the repairing material is improved, and fly-away loss caused by direct application of a powdery raw material is reduced. The slow-release repairing material for organochlorine pesticide contaminated farmland soil is suitable for repairing farmland soil contaminated with low-concentration organochlorine pesticides, and has a very broad application prospect.
Owner:农环科技(上海)有限公司

Method for removing trace cadmium from aqueous solution

The invention discloses a method for removing trace cadmium from an aqueous solution. The method comprises the following steps: culturing and analyzing plants growing in a chrome environment, adjusting the pH value of a cadmium-containing aqueous solution with acid or alkali; simultaneously or separately adding ferriferous reagents, carbonates and phosphates or molybdates into the aqueous solution; standing still for depositing, separating out cadmium-slag containing water, wherein the cadmium content of the cadmium-slag containing water is detected to be less than 0.01 mg/L. The method disclosed by the invention is characterized in that through controlling the adding amounts of the ferriferous reagents, the carbonates and the phosphates or the molybdates and the pH value of the cadmium-containing aqueous solution, trace cadmium elements in the cadmium-containing aqueous solution can be removed, and the water treatment time is short, adopted materials are economic and easy to obtain, and no harmful element is added into a system, therefore, the method is an environment-friendly and economic treatment process, and the process can be widely applied to the treatment of cadmium-containing wastewater discharged in the fields of the metal processing industry, the electroplating industry, the leather making industry and the textile industry, and the like.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY

Method for treating persistent halogenated hydrocarbons in soil by slow-release compound remediation agent

The invention discloses a method for treating persistent halogenated hydrocarbons in soil by a slow-release compound remediation agent. The method includes steps: pre-ploughing contaminated soil, directly spreading a certain quantity of the slow-release compound remediation agent into ploughed soil, harrowing to well mix, watering to keep certain moisture content, and covering the soil surface with a protecting layer to realize anaerobic reduction dehalogenation reaction, wherein spreading quantity of the remediation agent is 0.05-1.5% of the dry weight of the contaminated soil, the soil ploughing depth is 25-40cm, the soil moisture content is adjusted to 50-80% of maximum field moisture capacity after spreading of the remediation agent, and remediation treatment time is 30-350d. The remediation method takes advantages of great adsorption performance of black charcoal, efficient chemical reducibility of nano zero-valence metal and dissimilatory iron reduction dehalogenation performanceof functional microorganisms to achieve physical, chemical and biological synergistic remediation effects on persistent halogenated hydrocarbon contaminated soil and has advantages of long action period, structural stability, low cost, environmental friendliness and the like.
Owner:SHANGHAI ACADEMY OF ENVIRONMENTAL SCIENCES +2

Nano composite, preparation method and application thereof

The present invention discloses a nano composite. The nano composite is characterized by comprising photothermal conversion nanoparticles, a fusion agent, a paramagnetic component and an active targeting antibody; wherein the active targeting antibody contains carboxyl groups and the fusion agent contains amino groups; the carboxyl groups of the active targeting antibody is linked to the amino groups in the fusion agent. The nano composite has an active targeting property, integrates a magnetic effect and a photothermal effect in one, and particularly has better affinity for CD 133 receptor high-expression pancreatic cancer and related cancers. The present application also discloses a preparation method and an application of the nano composite. The method is mild in conditions, not high inrequirements on equipment, operation, environment, etc., economic and easily-obtained in raw materials, easy for implementation and good in stability and reproducibility. When the nano composite is used for magnetic resonance imaging and photothermal integration materials, the nano composite can effectively shorten T1 relaxation time, remarkably improves magnetic resonance T1 relaxation rate, andis better in T1 imaging, higher in contrast and also excellent in a near infrared photothermal effect.
Owner:THE AFFILIATED HOSPITAL OF MEDICAL SCHOOL NINGBO UNIV

Framework molecules based on folding and assembling of cyclic polymers and preparation method thereof

ActiveCN109705086AUnique Geometry CavityElasticOrganic chemistryPolyesterSolvent free
The invention discloses framework molecules based on folding and assembling of cyclic polymers and a preparation method thereof. The framework molecules have a chemical name of cyclic polyesters whichcomprise cyclic di-polyester namely 1-Ar, cyclic tri-polyester namely 2-Ar, cyclic tetra-polyester namely 3-Ar, cyclic penta-polyester namely 4-Ar and cyclic hexa-polyester namely 5-Ar, wherein Ar represents one selected from the group consisting of phenyl-1,4-diyl namely Ph, biphenyl-4,4'-diyl namely BP, 2,2-bipyridine-5,5'-diyl namely BPy and pyrene-2,7-diyl namely Pr, which have structural formulas as described in the specification. The preparation method for the framework molecules comprises the steps of carboxyl acylating chlorination with a thionyl chloride reflux method, ester exocondensation with a solvent-free method, and cyclic polyester separation with a gradient elution method. According to the invention, by utilization of the characteristic of formation of a nanometer cavitywith a larger size through intermolecular assembling, four series of cyclic polyester supramolecular host compounds are developed. The cyclic polyesters provided by the invention have the advantages of fewer synthetic steps, mild reaction conditions and low separation and purification cost.
Owner:HUNAN UNIV OF SCI & TECH

Sustained-release composite remediation agent for treating persistent halogenated hydrocarbon in groundwater and preparation method thereof

The invention discloses a sustained-release composite remediation agent for treating persistent halogenated hydrocarbon in groundwater and a preparation method thereof. The preparation method comprises the following steps: 1) preparing bacterial liquid saturated black carbon; 2) preparing a colloidal solution A containing locust bean gum and an organic carbon source; 3) preparing a colloidal suspension B containing locust bean gum, an organic carbon source, a nano-scale zero-valent metal and the bacterial liquid saturated black carbon; 4) carrying out a crosslinking reaction for 2-6h; and 5) carrying out a delayed crosslinking reaction for 2-6h to obtain a sustained-release composite remediation agent for treating persistent halogenated hydrocarbon in groundwater. The sustained-release composite remediation agent prepared by the method provided by the invention can utilize the good adsorption performance of black carbon, the high-efficiency chemical reducibility of the nano-scale zero-valent metal and the dissimilation iron reduction dehalogenation capability of functional microorganisms to achieve the physical, chemical and biological synergistic remediation effect of persistent halogenated hydrocarbon polluted groundwater, and has the advantages of long action period, stable structure, low cost, environmental friendliness and the like.
Owner:SHANGHAI ACADEMY OF ENVIRONMENTAL SCIENCES +1
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