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92results about How to "No "three wastes" discharge" patented technology

Method for comprehensively recovering valuable metals from copper anode sludge silver separating slag

The invention relates to a copper anode sludge silver separating slag reutilization technique, particularly a method for comprehensively recovering valuable metals from copper anode sludge silver separating slag. The method comprises the following steps: carrying out hot acid leaching on silver separating slag, filtering to obtain a hot acid leaching solution containing silver and barium and hot acid leaching slag containing tin and lead; diluting the hot acid leaching solution with water, filtering to obtain a precipitate, dissolving the precipitate with nitric acid, and filtering to obtain a barium sulfate precipitate and a silver nitrate solution; reducing the solution to obtain silver powder; leaching the hot acid leaching slag with acidic chlorine salt, filtering to obtain a chlorine salt leaching solution and chlorine salt leaching slag; cooling the chlorine salt leaching solution to crystallize and precipitate lead chloride; and carrying out alkali fusion, water immersion and evaporation crystallization on the chlorine salt leaching slag to obtain sodium stannate. The method can effectively recover all the valuable metals with higher content in the silver separating slag, and the recovery rates of the lead, silver, tin and barium are respectively up to higher than 97%, 92%, 90% and 95%. The method has the characteristics of simple technique, no emission of three wastes, high metal recovery rate and the like, and is suitable for large-scale industrial production.
Owner:JIANGXI UNIV OF SCI & TECH

Preparation method for active aluminosilicate

Belonging to the comprehensive utilization field of natural minerals, the invention provides a preparation method for active aluminosilicate. The method makes use of a sub-molten salt system to activate natural a silicon-aluminum mineral at low energy consumption and efficiently utilizes the activation product. The method adopts a high concentration alkaline solution as a medium to perform liquid phase activation reaction on a natural silicon-aluminum mineral so as to destroy the crystal structure of the natural silicon-aluminum mineral, thus forming the high activity aluminosilicate able to be used for molecular sieve synthesis. The decomposition temperature of the mineral is far below the roasting temperature of traditional thermal activation and alkali fusion activation, the crystal structure of the mineral can be fully destroyed at low temperature, simultaneous extraction of silicon and aluminum in the natural silicon-aluminum mineral can be realized, and the process is easy to operate. The method provided by the invention also extends the range of raw materials for molecular sieve preparation, not only greatly reduces the molecular sieve production cost, but also provides an effective way for high value added utilization of natural silicon-aluminum minerals.
Owner:CHINA UNIV OF PETROLEUM (BEIJING) +1

Method for synthesizing rubber vulcanization accelerator DM by oxygen oxidization

The invention discloses a method for synthesizing rubber vulcanization accelerator DM by oxygen oxidization. The process of the method comprises: adding a 95 to 99 mass percent accelerator MBT and a 10 to 25 mass percent aqueous ammonia into a three-neck flask in a molar ratio of 1:2-7 to dissolve the 95 to 99 mass percent accelerator MBT under the conditions of a temperature of 35 to 45 DEG C and a stirring speed of 10 to 100 r / min; after the MBT dissolves completely, adding the solution into a high-pressure oxidizing kettle; dissolving a copper sulfate catalyst in 10 to 20 grams of 10 to 25 mass percent of aqueous ammonia (the molar ratio of the catalyst to the MBT is 0.001-0.007:1) and adding the solution into the high-pressure oxidizing kettle; introducing oxygen into the high-pressure oxidizing kettle under the conditions of a reaction temperature of 40 to 70 DEG C and a stirring speed of 300 to 1,000 r / min to perform reaction for 1 to 5 hours under a condition of a reaction pressure of 0.2 to 0.7MPa till 0.2 to 0.7 hour after the oxygen introduction is stopped, wherein if the pressure in the high-pressure oxidizing kettle keeps constant, the reaction is finished; after the reaction is finished, reducing the pressure in the high-pressure oxidizing kettle to normal pressure; washing and drying the product to obtain a rubber vulcanization accelerator DM product; and distilling mother solution to recycle the aqueous ammonia. The purity of the product is up to over 98 percent. The invention has the advantages that: the method is simple in process and easy to industrialize; due to the recycling of the aqueous ammonia, the product has high quality and yield; and the synthesis process is free from the discharge of 'three wastes'.
Owner:内蒙古科迈化工有限公司

Vehicle shock absorber piston rod spraying technology

The invention relates to a vehicle shock absorber piston rod spraying technology. The vehicle shock absorber piston rod spraying technology comprises the following steps of: coarse grinding, degreasing, surface roughening, non-spraying surface protection, preheating, spraying and fine grinding. When a piston rod is treated according to the spraying technology provided by the invention, the performances such as the binding force, the coating intensity, the coating thickness, the abrasion resistance, the corrosion resistance and the like of a coating of the piston rod are all superior to those of a durionise layer, and the cost performance of the coating is also superior to that of the durionise layer, so that the technology is a precedence technology used for replacing a durionise technology; and particularly, the technology does not pollute the environment, is beneficial to improvement of the working environment and the health and the safety of an operator. The technology has the advantages that production period is short, production efficiency is high, defective rate is low, the treated vehicle shock absorber piston rod has good rust-proof performance, good abrasion resistance and long service life; moreover, automation operation is easily realized, production efficiency is high and the production cost is lowered.
Owner:NANYANG XIJIAN AUTOMOBILE SHOCK ABSORBER

Preparation method and device of methanol fuel finished gasoline for vehicles

The invention relates to a preparation method and device of methanol fuel finished gasoline for vehicles. The method provided by the invention comprises two steps of preparation of modified methanol and preparation of the methanol fuel finished gasoline for vehicles, wherein the preparation of the modified methanol is realized by the processes of proportioning, preheating, catalytic reaction and heat exchange of methanol and auxiliary materials; and the preparation of the methanol fuel finished gasoline for vehicles is finished by modulation of the modified methanol and modulation of the methanol fuel finished gasoline. The device provided by the invention sequentially comprises a mixer 2, a mixer 4, a catalytic reactor 5, a condensing, cooling and preheating device I1, a preheating and cooling device II3, a low-temperature cooler 6 and a receiving tank 7. Because an integrated device is designed for condensing, cooling and preheating raw materials, the invention ensures that the residual heat of reaction products is recycled, the process is simple and no emission of 'the three wastes' is realized; and simultaneously, the catalytic reactor is heated in a far-infrared radiation explosion-proof type, thus the invention has the advantages of obvious effects of energy saving, environmental protection and safety.
Owner:艾长江 +1

Preparation method and use method of modified bentonite environment-friendly formaldehyde removing agent

The invention relates to a modified bentonite environment-friendly formaldehyde removing agent for removing free formaldehyde in urea-formaldehyde glue. A preparation method of the formaldehyde removing agent comprises the following steps of: in parts by weight, crushing 100 parts of calcium bentonite, screening the crushed calcium bentonite through a 200-mesh sieve, adding 2 to 3.5 parts of sodium carbonate into the screened calcium bentonite, mixing uniformly, spraying water of which the weight accounts for 10 percent of that of the calcium bentonite, fully mixing uniformly, sealing the mixture for 24 hours for sodication reaction, and air-drying naturally; and adding 0.5 to 2.5 parts of hydroxyethyl cellulose, 1.5 to 2.5 parts of ammonia chloride and 2.5 to 5 parts of sodium nitrite into 100 parts of a raw material subjected to sodication, crushing the mixture and stirring for 3 hours to obtain powder, and screening the powder through a 300-mesh sieve to obtain formaldehyde removing powder. A use method of the modified bentonite environment-friendly formaldehyde removing agent comprises the following steps of: in parts by weight, adding 10 parts of water into 10 parts of the formaldehyde removing agent, stirring at a high speed for 40 minutes, adding 10 parts of a suspension of the mixture into 90 parts of the urea-formaldehyde glue, raising the temperature to 50 DEG C, fully stirring for 30 minutes, standing for more than 24 hours, and thus fully adsorbing the formaldehyde in the urea-formaldehyde glue. The modified bentonite environment-friendly formaldehyde removing agent has good adsorption effect on the formaldehyde, and cannot influence the performance of the urea-formaldehyde glue.
Owner:吕新民

Method for producing silkworm chrysalis peptide powder and silkworm chrysalis meal by aqueous biological enzyme method

The invention relates to a method for producing silkworm chrysalis peptide powder and silkworm chrysalis meal by an aqueous biological enzyme method. According to the method, silkworm chrysalises serve as raw materials, an enzymolysis solution is obtained through drying, crushing and carrying out aqueous-phase enzymolysis, a supernatant and residues are obtained through carrying out centrifugation on the enzymolysis solution, the silkworm chrysalis meal is obtained through drying and crushing the residues, and the silkworm chrysalis peptide powder is obtained through carrying out oil-water separation, ultrafiltration-membrane ultrafiltration and desalination on the supernatant and then drying and crushing. The method specifically comprises the following steps of (1) drying and crushing; (2) carrying out aqueous-phase enzymolysis; (3) carrying out centrifugation and oil-water separation; (4) carrying out ultrafiltration-membrane filtration; (5) carrying out desalination; (6) drying and crushing, thereby obtaining the silkworm chrysalis peptide powder. According to the method, the aqueous biological enzyme method is applied to insect cells-silkworm chrysalis cells for the first time; the method has the advantages that the process is simple, safe and environmental-friendly, the cost is low, the quality of the obtained silkworm chrysalis peptide powder and silkworm chrysalis meal is high, and the like; the method disclosed by the invention has the characteristics that the oil and fat removal efficiency is high, the residual fat content of the obtained silkworm chrysalis peptide powder and silkworm chrysalis meal is low, the oligopeptide content of the obtained silkworm chrysalis peptide powder and silkworm chrysalis meal is high, and the like.
Owner:ZHEJIANG ESIGMA BIOTECH CO LTD +1

Method for synthesizing grafted lysine viscose fibers

The invention provides a method for synthesizing grafted lysine viscose fibers and belongs to the technical field of modification of fiber materials. According to the method, commercially available viscose fibers and lysine are taken as raw materials, and the grafted lysine viscose fibers with good skin-friendly property, antibacterial property and dyeing property can be prepared stably through steps as follows: preparation of purified viscose fibers, preparation of carboxylated viscose fibers, preparation of ethylene glycol non-aqueous reaction media, preparation of the grafted lysine viscosefibers and preparation of purified ethylene glycol. The carboxylated viscose fibers and the grafted lysine viscose fibers are produced under catalysis of glucose oxidase and protease in sequence, thegrafted lysine viscose fibers are prepared in the ethylene glycol non-aqueous reaction media, reaction conditions are mild, reaction specificity and reaction efficiency are high, no by-products or three wastes are produced, and the method is a typical green production technology; the grafted lysine viscose fibers synthesized with the method are covered with amino acid, can be widely applied to the fields such as textiles, clothes, food and the like and have great social value and economic benefits.
Owner:CHONGQING UNIV

Special corrosion and scale inhibitor for water reuse in power plant and preparation method thereof

InactiveCN104843879ANo pollution in the processIncreased slow-release scale inhibition effectScale removal and water softeningEpoxySolubility
The invention relates to a special corrosion and scale inhibitor for water reuse in a power plant and a preparation method thereof. The special corrosion and scale inhibitor comprises the following components by weight percentage content: 25 to 40% of sulfonic methane amino poly epoxy succinic acid, 20 to 30% of N, N-diacetyl adipic dihydrazide, 12 to 30% of maleic acid-acrylic copolymer, 3 to 5% of graphene oxide aqueous dispersion, 3 to 6% of fatty alcohol-polyoxyethylene ether and 15 to 40% of zinc sulfate aqueous solution. The components of the corrosion and scale inhibitor achieve a synergistic effect, and can realize trace removal of pollutants, after the corrosion and scale inhibitor is compounded, the corrosion and scale inhibition properties are greatly improved, the synergistic effect of physical adsorption and chemical adsorption of the pollutants can be effectively realized, and the special corrosion and scale inhibitor can be used in a wider water pH scope and temperature, and has an excellent sterilizing effect. The production process is simple, three-waste emission is avoided, the stability and water solubility are good, and the main components are biodegradable, free of toxic, phosphorus, pollution and corrosivity, less in adding rate, and environment-friendly.
Owner:山东应天环保能源有限公司

Method and production system for continuous catalytic synthesis and separation of high-purity low-viscosity dimethyl silicone oil

The invention relates to a production method of cosmetic silicone oil, and in particular, relates to a method and production system for continuous catalytic synthesis and separation of high-purity low-viscosity dimethyl silicone oil. The method comprises the following steps: 1) a synthesis step; and 2) a separation step. The separation step comprises the steps: (1) discharging light components hexamethyldisiloxane and octamethyltrisiloxane from the tower top of a light component removal tower, condensing, enabling the condensed liquid to automatically flow to a low-boiling-point receiving tankof the light component removal tower, and conveying to an external low-boiling-point substance storage tank; and pumping heavy components at the bottom of the light component removal tower to a firstseparation tower; (2) discharging a component decamethyltetrasiloxane from the tower top of the first separation tower, and pumping a heavy component at the tower bottom to a second separation tower;(3) discharging a component dodecylmethylpentasiloxane from the tower top of the second separation tower, and pumping a heavy component at the tower bottom to a heavy component removal tower; and (4)discharging tetradecylmethylhexasiloxane from the tower top of the heavy component removal tower, and discharging a heavy component from the tower bottom of the heavy component removal tower. According to the method, continuous operation is carried out, and high-purity decamethyltetrasiloxane, dodecylmethylpentasiloxane and tetradecylmethylhexasiloxane can be prepared by continuously separating amixture through a separation tower.
Owner:RUNHE ORGANICSILICONE NEW MATERIAL
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